Influence of substituents in terephthalate linker on the structure of mofs obtained from presynthesized heterometallic complex

Marina Barsukova; Evgeny Dudko; Denis Samsonenko; Konstantin Kovalenko; Alexey Ryadun; Aleksandr Sapianik; Vladimir Fedin

doi:10.3390/inorganics9010004

Influence of substituents in terephthalate linker on the structure of mofs obtained from presynthesized heterometallic complex

Marina Barsukova, Evgeny Dudko, Denis Samsonenko, Konstantin Kovalenko, Alexey Ryadun, Aleksandr Sapianik^*, Vladimir Fedin

^*Corresponding author for this work

Advanced Membranes and Porous Materials Center

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The synthesis of new porous materials with desired properties is a challenging task. It becomes especially difficult if you need to combine several metals in one framework to obtain a heterometallic node. The use of presynthesized complexes for obtaining of new heterometallic metal–organic frameworks could be essential to solve the problem of tailored synthesis. In our study we use presynthesized heterometallic pivalate complex [Li₂Zn₂ (piv)₆ (py)₂ ] to obtain new MOFs with heterometallic core as a node of the framework. We are managed to obtain four new heterometallic MOFs: [H₂N(CH₃ )₂ ]₂ [Li₂Zn₂(bdc)₄ ]·CH₃CN·DMF (1), [Li₂Zn₂ (H₂Br₂-bdc)(Br₂-bdc)₃ ]·2DMF (2), [H₂N(CH₃ )₂ ][LiZn₂ (ndc)₃ ]·CH₃CN (3) and [{Li₂Zn₂ (dmf)(py)₂ }{LiZn(dmf)₂ }₂ (NO₂-bdc)₆ ]·5DMF (4). Moreover three of them contain starting tetranuclear core {Li₂Zn₂ } and saves its geometry. We also demonstrate the influence of substituent in terephthalate ring on preservation of tetranuclear core. For compound 1 it was shown that luminescence of the framework could be quenched when nitrobenzene is included in the pores.

Original language	English (US)
Article number	4
Pages (from-to)	1-15
Number of pages	15
Journal	Inorganics
Volume	9
Issue number	1
DOIs	https://doi.org/10.3390/inorganics9010004
State	Published - Jan 2021

Keywords

Heterometallic complexes
Luminescence
Metal–organic frameworks

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.3390/inorganics9010004

Cite this

@article{2332a1d46a784f52bc0ba0f6bc7f8cee,

title = "Influence of substituents in terephthalate linker on the structure of mofs obtained from presynthesized heterometallic complex",

abstract = "The synthesis of new porous materials with desired properties is a challenging task. It becomes especially difficult if you need to combine several metals in one framework to obtain a heterometallic node. The use of presynthesized complexes for obtaining of new heterometallic metal–organic frameworks could be essential to solve the problem of tailored synthesis. In our study we use presynthesized heterometallic pivalate complex [Li2Zn2 (piv)6 (py)2 ] to obtain new MOFs with heterometallic core as a node of the framework. We are managed to obtain four new heterometallic MOFs: [H2N(CH3 )2 ]2 [Li2Zn2(bdc)4 ]·CH3CN·DMF (1), [Li2Zn2 (H2Br2-bdc)(Br2-bdc)3 ]·2DMF (2), [H2N(CH3 )2 ][LiZn2 (ndc)3 ]·CH3CN (3) and [{Li2Zn2 (dmf)(py)2 }{LiZn(dmf)2 }2 (NO2-bdc)6 ]·5DMF (4). Moreover three of them contain starting tetranuclear core {Li2Zn2 } and saves its geometry. We also demonstrate the influence of substituent in terephthalate ring on preservation of tetranuclear core. For compound 1 it was shown that luminescence of the framework could be quenched when nitrobenzene is included in the pores.",

keywords = "Heterometallic complexes, Luminescence, Metal–organic frameworks",

author = "Marina Barsukova and Evgeny Dudko and Denis Samsonenko and Konstantin Kovalenko and Alexey Ryadun and Aleksandr Sapianik and Vladimir Fedin",

note = "Funding Information: Funding: This research was funded by The Russian Science Foundation, grant number 19-73-00171. Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = jan,

doi = "10.3390/inorganics9010004",

language = "English (US)",

volume = "9",

pages = "1--15",

journal = "Inorganics",

issn = "2304-6740",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "1",

}

TY - JOUR

T1 - Influence of substituents in terephthalate linker on the structure of mofs obtained from presynthesized heterometallic complex

AU - Barsukova, Marina

AU - Dudko, Evgeny

AU - Samsonenko, Denis

AU - Kovalenko, Konstantin

AU - Ryadun, Alexey

AU - Sapianik, Aleksandr

AU - Fedin, Vladimir

PY - 2021/1

Y1 - 2021/1

N2 - The synthesis of new porous materials with desired properties is a challenging task. It becomes especially difficult if you need to combine several metals in one framework to obtain a heterometallic node. The use of presynthesized complexes for obtaining of new heterometallic metal–organic frameworks could be essential to solve the problem of tailored synthesis. In our study we use presynthesized heterometallic pivalate complex [Li2Zn2 (piv)6 (py)2 ] to obtain new MOFs with heterometallic core as a node of the framework. We are managed to obtain four new heterometallic MOFs: [H2N(CH3 )2 ]2 [Li2Zn2(bdc)4 ]·CH3CN·DMF (1), [Li2Zn2 (H2Br2-bdc)(Br2-bdc)3 ]·2DMF (2), [H2N(CH3 )2 ][LiZn2 (ndc)3 ]·CH3CN (3) and [{Li2Zn2 (dmf)(py)2 }{LiZn(dmf)2 }2 (NO2-bdc)6 ]·5DMF (4). Moreover three of them contain starting tetranuclear core {Li2Zn2 } and saves its geometry. We also demonstrate the influence of substituent in terephthalate ring on preservation of tetranuclear core. For compound 1 it was shown that luminescence of the framework could be quenched when nitrobenzene is included in the pores.

AB - The synthesis of new porous materials with desired properties is a challenging task. It becomes especially difficult if you need to combine several metals in one framework to obtain a heterometallic node. The use of presynthesized complexes for obtaining of new heterometallic metal–organic frameworks could be essential to solve the problem of tailored synthesis. In our study we use presynthesized heterometallic pivalate complex [Li2Zn2 (piv)6 (py)2 ] to obtain new MOFs with heterometallic core as a node of the framework. We are managed to obtain four new heterometallic MOFs: [H2N(CH3 )2 ]2 [Li2Zn2(bdc)4 ]·CH3CN·DMF (1), [Li2Zn2 (H2Br2-bdc)(Br2-bdc)3 ]·2DMF (2), [H2N(CH3 )2 ][LiZn2 (ndc)3 ]·CH3CN (3) and [{Li2Zn2 (dmf)(py)2 }{LiZn(dmf)2 }2 (NO2-bdc)6 ]·5DMF (4). Moreover three of them contain starting tetranuclear core {Li2Zn2 } and saves its geometry. We also demonstrate the influence of substituent in terephthalate ring on preservation of tetranuclear core. For compound 1 it was shown that luminescence of the framework could be quenched when nitrobenzene is included in the pores.

KW - Heterometallic complexes

KW - Luminescence

KW - Metal–organic frameworks

UR - http://www.scopus.com/inward/record.url?scp=85099799093&partnerID=8YFLogxK

U2 - 10.3390/inorganics9010004

DO - 10.3390/inorganics9010004

M3 - Article

AN - SCOPUS:85099799093

SN - 2304-6740

VL - 9

SP - 1

EP - 15

JO - Inorganics

JF - Inorganics

IS - 1

M1 - 4

ER -

Influence of substituents in terephthalate linker on the structure of mofs obtained from presynthesized heterometallic complex

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this