Interplay of metal node and amine functionality in NH2-MIL-53: Modulating breathing behavior through intra-framework interactions

Pablo Serra-Crespo; Elena Gobechiya; Enrique V. Ramos-Fernandez; Jana Juan-Alcañiz; Alberto Martinez-Joaristi; Eli Stavitski; Christine E.A. Kirschhock; Johan A. Martens; Freek Kapteijn; Jorge Gascon

doi:10.1021/la302824j

Interplay of metal node and amine functionality in NH₂-MIL-53: Modulating breathing behavior through intra-framework interactions

Pablo Serra-Crespo, Elena Gobechiya, Enrique V. Ramos-Fernandez, Jana Juan-Alcañiz, Alberto Martinez-Joaristi, Eli Stavitski, Christine E.A. Kirschhock, Johan A. Martens, Freek Kapteijn, Jorge Gascon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between the amines of the organic linker and bridging μ₂-OH of the inorganic scaffold modulates metal organic framework (MOF) flexibility. The strength of the interaction has been found to correlate with the electropositivity of the metal.

Original language	English (US)
Pages (from-to)	12916-12922
Number of pages	7
Journal	LANGMUIR
Volume	28
Issue number	35
DOIs	https://doi.org/10.1021/la302824j
State	Published - Sep 4 2012
Externally published	Yes

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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10.1021/la302824j

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Serra-Crespo, P., Gobechiya, E., Ramos-Fernandez, E. V., Juan-Alcañiz, J., Martinez-Joaristi, A., Stavitski, E., Kirschhock, C. E. A., Martens, J. A., Kapteijn, F., & Gascon, J. (2012). Interplay of metal node and amine functionality in NH₂-MIL-53: Modulating breathing behavior through intra-framework interactions. LANGMUIR, 28(35), 12916-12922. https://doi.org/10.1021/la302824j

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title = "Interplay of metal node and amine functionality in NH2-MIL-53: Modulating breathing behavior through intra-framework interactions",

abstract = "A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between the amines of the organic linker and bridging μ2-OH of the inorganic scaffold modulates metal organic framework (MOF) flexibility. The strength of the interaction has been found to correlate with the electropositivity of the metal.",

author = "Pablo Serra-Crespo and Elena Gobechiya and Ramos-Fernandez, {Enrique V.} and Jana Juan-Alca{\~n}iz and Alberto Martinez-Joaristi and Eli Stavitski and Kirschhock, {Christine E.A.} and Martens, {Johan A.} and Freek Kapteijn and Jorge Gascon",

year = "2012",

month = sep,

day = "4",

doi = "10.1021/la302824j",

language = "English (US)",

volume = "28",

pages = "12916--12922",

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Serra-Crespo, P, Gobechiya, E, Ramos-Fernandez, EV, Juan-Alcañiz, J, Martinez-Joaristi, A, Stavitski, E, Kirschhock, CEA, Martens, JA, Kapteijn, F & Gascon, J 2012, 'Interplay of metal node and amine functionality in NH₂-MIL-53: Modulating breathing behavior through intra-framework interactions', LANGMUIR, vol. 28, no. 35, pp. 12916-12922. https://doi.org/10.1021/la302824j

TY - JOUR

T1 - Interplay of metal node and amine functionality in NH2-MIL-53

T2 - Modulating breathing behavior through intra-framework interactions

AU - Serra-Crespo, Pablo

AU - Gobechiya, Elena

AU - Ramos-Fernandez, Enrique V.

AU - Juan-Alcañiz, Jana

AU - Martinez-Joaristi, Alberto

AU - Stavitski, Eli

AU - Kirschhock, Christine E.A.

AU - Martens, Johan A.

AU - Kapteijn, Freek

AU - Gascon, Jorge

PY - 2012/9/4

Y1 - 2012/9/4

N2 - A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between the amines of the organic linker and bridging μ2-OH of the inorganic scaffold modulates metal organic framework (MOF) flexibility. The strength of the interaction has been found to correlate with the electropositivity of the metal.

AB - A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between the amines of the organic linker and bridging μ2-OH of the inorganic scaffold modulates metal organic framework (MOF) flexibility. The strength of the interaction has been found to correlate with the electropositivity of the metal.

UR - http://www.scopus.com/inward/record.url?scp=84865798071&partnerID=8YFLogxK

U2 - 10.1021/la302824j

DO - 10.1021/la302824j

M3 - Article

C2 - 22891682

AN - SCOPUS:84865798071

SN - 0743-7463

VL - 28

SP - 12916

EP - 12922

JO - LANGMUIR

JF - LANGMUIR

IS - 35

ER -

Interplay of metal node and amine functionality in NH₂-MIL-53: Modulating breathing behavior through intra-framework interactions

Abstract

ASJC Scopus subject areas

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