I.R. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl

Bernard Besson; B. Moraweck; A. K. Smith; J. M. Basset; Rinaldo Psaro; A. Fusi; R. Ugo

doi:10.1039/c39800000569

I.R. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl

Bernard Besson, B. Moraweck, A. K. Smith, J. M. Basset^*, Rinaldo Psaro, A. Fusi, R. Ugo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

Os₃(CO)₁₂ and Os₃(CO)₁₀(MeCN) ₂ react with silanol groups of silica at 160 and 25°C, respectively, to give the grafted cluster Os₃(CO)₁₀(H) (OSi3 bonds on the leftside sign) (1) which has been characterized by i.r. spectroscopy, gas phase analysis, and E.X.A.F.S.; the model compound Os ₃-(CO)₁₀(H)(OSiPh₃), obtained by the reaction of Os₃-(CO)₁₂ with Ph₃SiOH, confirms the structure of the surface compound (1).

Original language	English (US)
Pages (from-to)	569-571
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/c39800000569
State	Published - 1980
Externally published	Yes

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title = "I.R. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl",

abstract = "Os3(CO)12 and Os3(CO)10(MeCN) 2 react with silanol groups of silica at 160 and 25°C, respectively, to give the grafted cluster Os3(CO)10(H) (OSi3 bonds on the leftside sign) (1) which has been characterized by i.r. spectroscopy, gas phase analysis, and E.X.A.F.S.; the model compound Os 3-(CO)10(H)(OSiPh3), obtained by the reaction of Os3-(CO)12 with Ph3SiOH, confirms the structure of the surface compound (1).",

author = "Bernard Besson and B. Moraweck and Smith, {A. K.} and Basset, {J. M.} and Rinaldo Psaro and A. Fusi and R. Ugo",

year = "1980",

doi = "10.1039/c39800000569",

language = "English (US)",

pages = "569--571",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - I.R. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl

AU - Besson, Bernard

AU - Moraweck, B.

AU - Smith, A. K.

AU - Basset, J. M.

AU - Psaro, Rinaldo

AU - Fusi, A.

AU - Ugo, R.

PY - 1980

Y1 - 1980

N2 - Os3(CO)12 and Os3(CO)10(MeCN) 2 react with silanol groups of silica at 160 and 25°C, respectively, to give the grafted cluster Os3(CO)10(H) (OSi3 bonds on the leftside sign) (1) which has been characterized by i.r. spectroscopy, gas phase analysis, and E.X.A.F.S.; the model compound Os 3-(CO)10(H)(OSiPh3), obtained by the reaction of Os3-(CO)12 with Ph3SiOH, confirms the structure of the surface compound (1).

AB - Os3(CO)12 and Os3(CO)10(MeCN) 2 react with silanol groups of silica at 160 and 25°C, respectively, to give the grafted cluster Os3(CO)10(H) (OSi3 bonds on the leftside sign) (1) which has been characterized by i.r. spectroscopy, gas phase analysis, and E.X.A.F.S.; the model compound Os 3-(CO)10(H)(OSiPh3), obtained by the reaction of Os3-(CO)12 with Ph3SiOH, confirms the structure of the surface compound (1).

UR - http://www.scopus.com/inward/record.url?scp=37049108593&partnerID=8YFLogxK

U2 - 10.1039/c39800000569

DO - 10.1039/c39800000569

M3 - Article

AN - SCOPUS:37049108593

SN - 0022-4936

SP - 569

EP - 571

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 12

ER -

I.R. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl

Abstract

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