Kinetics and thermodynamics of small molecule binding to pincer-PCP rhodium(I) complexes

Chemistry

• Rhodium 100%
• Ethylene 100%
• NMR Spectroscopy 100%
• Cyclohexane 100%
• Density Functional Theory 50%
• Rate Constant 50%
• UV/VIS Spectroscopy 50%
• Flash Photolysis 50%
• Free Energy of Binding 50%
• Conformational Isomer 50%
• Structure 50%
• Absorption Spectroscopy 50%

Keyphrases

• Small Molecule Binding 100%
• Parallel Reactions 50%
• Coordinating Solvents 50%
• Competing Pathway 50%
• PCP Ligands 50%
• Direct Reactions 50%
• Control Rate 50%
• Three-coordinate 50%
• Equilibrium Density 50%
• Flash Photolysis 50%
• Time-resolved Infrared 50%
• Gas Monitoring 50%
• Relative Free Energy 50%
• Equilibrium Studies 50%

Biochemistry, Genetics and Molecular Biology

• Small Molecule 100%
• Facilitated Diffusion 50%
• Absorption Spectroscopy 50%
• Infrared Radiation 50%
• Organic Solvents 50%
• Solution and Solubility 50%
• Flash Photolysis 50%