TY - JOUR
T1 - Lanthanide metal organic frameworks based on octahedral secondary building units: Structural, luminescent, and magnetic properties
AU - Zhang, Hua Bin
AU - Peng, Yan
AU - Shan, Xiao Chen
AU - Tian, Chong Bin
AU - Ping-Lin, null
AU - Du, Shao Wu
N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15
PY - 2011/7/1
Y1 - 2011/7/1
N2 - Three new lanthanide metal organic frameworks (LnMOFs), [HNMe 2][Ln2(m-BDC)3(phen)2] (Ln = Eu 1, Gd 2, Tb 3, m-H2BDC = 1,3-benzenedicarboxylic acid, phen = 1,10-phenanthroline), have been solvothermally synthesized through self-assembly reactions. Complexes 1-3 are isostructural and possess 3D architectures based on the octahedral [Ln2(COO)6] SBUs with a pcu net topology. Photoluminescence measurements show that 1 and 3 are highly emissive at room temperature with quantum yields of 86.87% (at 330 nm) and 85.62% (at 345 nm), respectively, and may be good candidates for light-emitting diodes (LEDs) and light applications. The magnetic properties of 2 and 3 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2011 Elsevier B.V.
AB - Three new lanthanide metal organic frameworks (LnMOFs), [HNMe 2][Ln2(m-BDC)3(phen)2] (Ln = Eu 1, Gd 2, Tb 3, m-H2BDC = 1,3-benzenedicarboxylic acid, phen = 1,10-phenanthroline), have been solvothermally synthesized through self-assembly reactions. Complexes 1-3 are isostructural and possess 3D architectures based on the octahedral [Ln2(COO)6] SBUs with a pcu net topology. Photoluminescence measurements show that 1 and 3 are highly emissive at room temperature with quantum yields of 86.87% (at 330 nm) and 85.62% (at 345 nm), respectively, and may be good candidates for light-emitting diodes (LEDs) and light applications. The magnetic properties of 2 and 3 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2011 Elsevier B.V.
UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700311002103
UR - http://www.scopus.com/inward/record.url?scp=79957614124&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2011.04.014
DO - 10.1016/j.inoche.2011.04.014
M3 - Article
SN - 1387-7003
VL - 14
SP - 1165
EP - 1169
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 7
ER -