Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

O. Shekhah; H. Wang; T. Strunskus; P. Cyganik; D. Zacher; R. Fischer; C. Wöll

doi:10.1021/la701148z

Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

O. Shekhah^*, H. Wang, T. Strunskus, P. Cyganik, D. Zacher, R. Fischer, C. Wöll

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

123 Scopus citations

Abstract

A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH₃. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.

Original language	English (US)
Pages (from-to)	7440-7442
Number of pages	3
Journal	LANGMUIR
Volume	23
Issue number	14
DOIs	https://doi.org/10.1021/la701148z
State	Published - Jul 3 2007
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Spectroscopy
General Materials Science
Surfaces and Interfaces
Electrochemistry

Access to Document

10.1021/la701148z

Cite this

@article{0063e7b128ca47289f451ae8259db7df,

title = "Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface",

abstract = "A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.",

author = "O. Shekhah and H. Wang and T. Strunskus and P. Cyganik and D. Zacher and R. Fischer and C. W{\"o}ll",

year = "2007",

month = jul,

day = "3",

doi = "10.1021/la701148z",

language = "English (US)",

volume = "23",

pages = "7440--7442",

journal = "LANGMUIR",

issn = "0743-7463",

publisher = "American Chemical Society",

number = "14",

}

TY - JOUR

T1 - Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

AU - Shekhah, O.

AU - Wang, H.

AU - Strunskus, T.

AU - Cyganik, P.

AU - Zacher, D.

AU - Fischer, R.

AU - Wöll, C.

PY - 2007/7/3

Y1 - 2007/7/3

N2 - A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.

AB - A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.

UR - http://www.scopus.com/inward/record.url?scp=34547193751&partnerID=8YFLogxK

U2 - 10.1021/la701148z

DO - 10.1021/la701148z

M3 - Article

C2 - 17542626

AN - SCOPUS:34547193751

SN - 0743-7463

VL - 23

SP - 7440

EP - 7442

JO - LANGMUIR

JF - LANGMUIR

IS - 14

ER -

Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this