Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

Umesh Patil; Youssef Saih; Edy Abou-Hamad; Ali Imad Ali Hamieh; Jeremie Pelletier; Jean-Marie Basset

doi:10.1039/c4cc04950k

Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

Umesh Patil, Youssef Saih, Edy Abou-Hamad, Ali Imad Ali Hamieh, Jeremie Pelletier, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. This journal is

Original language	English (US)
Pages (from-to)	12348-12351
Number of pages	4
Journal	Chem. Commun.
Volume	50
Issue number	82
DOIs	https://doi.org/10.1039/c4cc04950k
State	Published - 2014

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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abstract = "A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. This journal is",

author = "Umesh Patil and Youssef Saih and Edy Abou-Hamad and Hamieh, {Ali Imad Ali} and Jeremie Pelletier and Jean-Marie Basset",

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AU - Patil, Umesh

AU - Saih, Youssef

AU - Abou-Hamad, Edy

AU - Hamieh, Ali Imad Ali

AU - Pelletier, Jeremie

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We gratefully acknowledge King Abdullah University of Science and Technology (KAUST) and Saudi Basic Industries Corporation (SABIC) for financial support.

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AB - A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. This journal is

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Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

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