Luminescent, second-order NLO and magnetic properties of the hydrogen-bond based network derived from 2,2′-bipyridine-6,6′-dicarboxylate

Xiaochen Shan; A. O. Ibrahim; Youfu Zhou; Huabin Zhang; Jie Ma; Feilong Jiang; Maochun Hong

doi:10.1016/j.inoche.2012.05.048

Luminescent, second-order NLO and magnetic properties of the hydrogen-bond based network derived from 2,2′-bipyridine-6,6′-dicarboxylate

Xiaochen Shan, A. O. Ibrahim, Youfu Zhou, Huabin Zhang, Jie Ma, Feilong Jiang, Maochun Hong

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Complexes [Zn(bpdc)(H 2O) 2] (1) and [Mn(bpdc)(H 2O) 3]·2.5H 2O (2) were assembled by 2,2′-bipyridine-6,6′-dicarboxylate (H 2bpdc) with Zn 2+ or Mn 2+ under hydro/solvo-thermal conditions. Complexes 1 and 2 are extended from mononuclear to 1D, 2D and 3D supramolecular network step by step with the help of intramolecular weak interactions. The luminescent properties of 1 had been investigated in details, which show intense blue emission with relatively good quantum yield. The 2 displays nonlinear optical (NLO) activity comparable with that of KDP, and exhibits weak antiferromagnetic coupling between the Mn (II) ions by the hydrogen bonds. © 2012 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	149-153
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	22
DOIs	https://doi.org/10.1016/j.inoche.2012.05.048
State	Published - Aug 1 2012
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1016/j.inoche.2012.05.048

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title = "Luminescent, second-order NLO and magnetic properties of the hydrogen-bond based network derived from 2,2′-bipyridine-6,6′-dicarboxylate",

abstract = "Complexes [Zn(bpdc)(H 2O) 2] (1) and [Mn(bpdc)(H 2O) 3]·2.5H 2O (2) were assembled by 2,2′-bipyridine-6,6′-dicarboxylate (H 2bpdc) with Zn 2+ or Mn 2+ under hydro/solvo-thermal conditions. Complexes 1 and 2 are extended from mononuclear to 1D, 2D and 3D supramolecular network step by step with the help of intramolecular weak interactions. The luminescent properties of 1 had been investigated in details, which show intense blue emission with relatively good quantum yield. The 2 displays nonlinear optical (NLO) activity comparable with that of KDP, and exhibits weak antiferromagnetic coupling between the Mn (II) ions by the hydrogen bonds. {\textcopyright} 2012 Elsevier B.V. All rights reserved.",

author = "Xiaochen Shan and Ibrahim, {A. O.} and Youfu Zhou and Huabin Zhang and Jie Ma and Feilong Jiang and Maochun Hong",

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doi = "10.1016/j.inoche.2012.05.048",

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T1 - Luminescent, second-order NLO and magnetic properties of the hydrogen-bond based network derived from 2,2′-bipyridine-6,6′-dicarboxylate

AU - Shan, Xiaochen

AU - Ibrahim, A. O.

AU - Zhou, Youfu

AU - Zhang, Huabin

AU - Ma, Jie

AU - Jiang, Feilong

AU - Hong, Maochun

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2012/8/1

Y1 - 2012/8/1

N2 - Complexes [Zn(bpdc)(H 2O) 2] (1) and [Mn(bpdc)(H 2O) 3]·2.5H 2O (2) were assembled by 2,2′-bipyridine-6,6′-dicarboxylate (H 2bpdc) with Zn 2+ or Mn 2+ under hydro/solvo-thermal conditions. Complexes 1 and 2 are extended from mononuclear to 1D, 2D and 3D supramolecular network step by step with the help of intramolecular weak interactions. The luminescent properties of 1 had been investigated in details, which show intense blue emission with relatively good quantum yield. The 2 displays nonlinear optical (NLO) activity comparable with that of KDP, and exhibits weak antiferromagnetic coupling between the Mn (II) ions by the hydrogen bonds. © 2012 Elsevier B.V. All rights reserved.

AB - Complexes [Zn(bpdc)(H 2O) 2] (1) and [Mn(bpdc)(H 2O) 3]·2.5H 2O (2) were assembled by 2,2′-bipyridine-6,6′-dicarboxylate (H 2bpdc) with Zn 2+ or Mn 2+ under hydro/solvo-thermal conditions. Complexes 1 and 2 are extended from mononuclear to 1D, 2D and 3D supramolecular network step by step with the help of intramolecular weak interactions. The luminescent properties of 1 had been investigated in details, which show intense blue emission with relatively good quantum yield. The 2 displays nonlinear optical (NLO) activity comparable with that of KDP, and exhibits weak antiferromagnetic coupling between the Mn (II) ions by the hydrogen bonds. © 2012 Elsevier B.V. All rights reserved.

UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700312002675

UR - http://www.scopus.com/inward/record.url?scp=84863336278&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2012.05.048

DO - 10.1016/j.inoche.2012.05.048

M3 - Article

SN - 1387-7003

VL - 22

SP - 149

EP - 153

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Luminescent, second-order NLO and magnetic properties of the hydrogen-bond based network derived from 2,2′-bipyridine-6,6′-dicarboxylate

Abstract

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