Abstract
The discovery of living anionic polymerization by Szwarc 50 years ago opened the way to the synthesis of model polymers. This ground-breaking discovery inspired many researchers to develop controlled/living routes for a plethora of monomers including those not compatible with anionic polymerization. These methods and their combinations serve as an arsenal for the synthesis of well-defined polymeric materials with predetermined properties and a rich variety of applications. A few representative examples of living and controlled/living methodologies for the synthesis of polymers with different macromolecular architectures are presented in this review.
Original language | English (US) |
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Pages (from-to) | 1068-1132 |
Number of pages | 65 |
Journal | Progress in Polymer Science (Oxford) |
Volume | 31 |
Issue number | 12 |
DOIs | |
State | Published - Dec 2006 |
Externally published | Yes |
Keywords
- Controlled polymerization
- Living polymerization
- Macromolecular architecture
ASJC Scopus subject areas
- Ceramics and Composites
- Surfaces and Interfaces
- Polymers and Plastics
- Organic Chemistry
- Materials Chemistry