Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes

Marc Magre; Marcin Szewczyk; Magnus Rueping

doi:10.1021/acs.orglett.0c00184

Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes

Marc Magre, Marcin Szewczyk, Magnus Rueping

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Abstract

A regio- and stereoselective magnesium-catalyzed hydrostannylation of internal and terminal alkynes has been developed. Excellent yields and selectivities are obtained for a wide range of terminal and internal symmetrical and unsymmetrical alkynes by using this alkaline earth metal catalyst as an effective alternative to transition metal catalysts.

Original language	English (US)
Journal	Organic Letters
DOIs	https://doi.org/10.1021/acs.orglett.0c00184
State	Published - Feb 5 2020

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10.1021/acs.orglett.0c00184

https://repository.kaust.edu.sa/bitstream/10754/661460/1/Manuscript-revised.pdf

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title = "Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes",

abstract = "A regio- and stereoselective magnesium-catalyzed hydrostannylation of internal and terminal alkynes has been developed. Excellent yields and selectivities are obtained for a wide range of terminal and internal symmetrical and unsymmetrical alkynes by using this alkaline earth metal catalyst as an effective alternative to transition metal catalysts.",

author = "Marc Magre and Marcin Szewczyk and Magnus Rueping",

note = "KAUST Repository Item: Exported on 2020-10-01",

year = "2020",

month = feb,

day = "5",

doi = "10.1021/acs.orglett.0c00184",

language = "English (US)",

journal = "Organic Letters",

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T1 - Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes

AU - Magre, Marc

AU - Szewczyk, Marcin

AU - Rueping, Magnus

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2020/2/5

Y1 - 2020/2/5

N2 - A regio- and stereoselective magnesium-catalyzed hydrostannylation of internal and terminal alkynes has been developed. Excellent yields and selectivities are obtained for a wide range of terminal and internal symmetrical and unsymmetrical alkynes by using this alkaline earth metal catalyst as an effective alternative to transition metal catalysts.

AB - A regio- and stereoselective magnesium-catalyzed hydrostannylation of internal and terminal alkynes has been developed. Excellent yields and selectivities are obtained for a wide range of terminal and internal symmetrical and unsymmetrical alkynes by using this alkaline earth metal catalyst as an effective alternative to transition metal catalysts.

UR - http://hdl.handle.net/10754/661460

UR - https://pubs.acs.org/doi/10.1021/acs.orglett.0c00184

UR - http://www.scopus.com/inward/record.url?scp=85079545140&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.0c00184

DO - 10.1021/acs.orglett.0c00184

M3 - Article

C2 - 32023069

SN - 1523-7060

JO - Organic Letters

JF - Organic Letters

ER -

Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes

Abstract

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