Magnetic properties of cyano-bridged Ln3+-M3+ complexes. Part I: Trinuclear complexes (Ln3+ = La, Ce, Pr, Nd, Sm; M3+ = FeLS, Co) with bpy as blocking ligand

Albert Figuerola; Joan Ribas; Miquel Llunell; David Casanova; Miguel Maestro; Santiago Alvarez; Carmen Diaz

doi:10.1021/ic050648i

Magnetic properties of cyano-bridged Ln³⁺-M³⁺ complexes. Part I: Trinuclear complexes (Ln³⁺ = La, Ce, Pr, Nd, Sm; M³⁺ = Fe_LS, Co) with bpy as blocking ligand

Albert Figuerola, Joan Ribas, Miquel Llunell, David Casanova, Miguel Maestro, Santiago Alvarez^*, Carmen Diaz

^*Corresponding author for this work

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Abstract

The reaction of Ln(NO₃)_3(aq) with K ₃[Fe(CN)₆] or K₃[Co(CN)₆] and 2,2′-bipyridine in water/ethanol led to eight trinuclear complexes: trans-[M(CN)₄(μ-CN)₂{Ln(H₂O) ₄(bpy)₂}₂][M(CN)₆]·8H ₂O (M = Fe³⁺ or Co³⁺, Ln = La³⁺, Ce³⁺, Pr³⁺, Nd³⁺, and Sm³⁺). The structures for the eight complexes [La₂Fe] (1), [Ce₂Fe] (2), [Pr₂Fe] (3), [Nd₂Fe] (4), [Ce₂Co] (5), [Pr₂Co] (6), [Nd₂Co] (7), and [Sm₂Co] (8) have been solved; they crystallize in the triclinic space group P1 and are isomorphous. They exhibit a supramolecular 3D architecture through hydrogen bonding and π-π stacking interactions. A stereochemical study of the nine-vertex polyhedra of the lanthanide ions, based on continuous shape measures, is presented. No significant magnetic interaction was found between the lanthanide(III) and the iron(III) ions.

Original language	English (US)
Pages (from-to)	6939-6948
Number of pages	10
Journal	Inorganic chemistry
Volume	44
Issue number	20
DOIs	https://doi.org/10.1021/ic050648i
State	Published - Oct 3 2005
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{9325d567c8f4426aa44af644347a3b1e,

title = "Magnetic properties of cyano-bridged Ln3+-M3+ complexes. Part I: Trinuclear complexes (Ln3+ = La, Ce, Pr, Nd, Sm; M3+ = FeLS, Co) with bpy as blocking ligand",

abstract = "The reaction of Ln(NO3)3(aq) with K 3[Fe(CN)6] or K3[Co(CN)6] and 2,2′-bipyridine in water/ethanol led to eight trinuclear complexes: trans-[M(CN)4(μ-CN)2{Ln(H2O) 4(bpy)2}2][M(CN)6]·8H 2O (M = Fe3+ or Co3+, Ln = La3+, Ce3+, Pr3+, Nd3+, and Sm3+). The structures for the eight complexes [La2Fe] (1), [Ce2Fe] (2), [Pr2Fe] (3), [Nd2Fe] (4), [Ce2Co] (5), [Pr2Co] (6), [Nd2Co] (7), and [Sm2Co] (8) have been solved; they crystallize in the triclinic space group P1 and are isomorphous. They exhibit a supramolecular 3D architecture through hydrogen bonding and π-π stacking interactions. A stereochemical study of the nine-vertex polyhedra of the lanthanide ions, based on continuous shape measures, is presented. No significant magnetic interaction was found between the lanthanide(III) and the iron(III) ions.",

author = "Albert Figuerola and Joan Ribas and Miquel Llunell and David Casanova and Miguel Maestro and Santiago Alvarez and Carmen Diaz",

year = "2005",

month = oct,

day = "3",

doi = "10.1021/ic050648i",

language = "English (US)",

volume = "44",

pages = "6939--6948",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Magnetic properties of cyano-bridged Ln3+-M3+ complexes. Part I

T2 - Trinuclear complexes (Ln3+ = La, Ce, Pr, Nd, Sm; M3+ = FeLS, Co) with bpy as blocking ligand

AU - Figuerola, Albert

AU - Ribas, Joan

AU - Llunell, Miquel

AU - Casanova, David

AU - Maestro, Miguel

AU - Alvarez, Santiago

AU - Diaz, Carmen

PY - 2005/10/3

Y1 - 2005/10/3

N2 - The reaction of Ln(NO3)3(aq) with K 3[Fe(CN)6] or K3[Co(CN)6] and 2,2′-bipyridine in water/ethanol led to eight trinuclear complexes: trans-[M(CN)4(μ-CN)2{Ln(H2O) 4(bpy)2}2][M(CN)6]·8H 2O (M = Fe3+ or Co3+, Ln = La3+, Ce3+, Pr3+, Nd3+, and Sm3+). The structures for the eight complexes [La2Fe] (1), [Ce2Fe] (2), [Pr2Fe] (3), [Nd2Fe] (4), [Ce2Co] (5), [Pr2Co] (6), [Nd2Co] (7), and [Sm2Co] (8) have been solved; they crystallize in the triclinic space group P1 and are isomorphous. They exhibit a supramolecular 3D architecture through hydrogen bonding and π-π stacking interactions. A stereochemical study of the nine-vertex polyhedra of the lanthanide ions, based on continuous shape measures, is presented. No significant magnetic interaction was found between the lanthanide(III) and the iron(III) ions.

AB - The reaction of Ln(NO3)3(aq) with K 3[Fe(CN)6] or K3[Co(CN)6] and 2,2′-bipyridine in water/ethanol led to eight trinuclear complexes: trans-[M(CN)4(μ-CN)2{Ln(H2O) 4(bpy)2}2][M(CN)6]·8H 2O (M = Fe3+ or Co3+, Ln = La3+, Ce3+, Pr3+, Nd3+, and Sm3+). The structures for the eight complexes [La2Fe] (1), [Ce2Fe] (2), [Pr2Fe] (3), [Nd2Fe] (4), [Ce2Co] (5), [Pr2Co] (6), [Nd2Co] (7), and [Sm2Co] (8) have been solved; they crystallize in the triclinic space group P1 and are isomorphous. They exhibit a supramolecular 3D architecture through hydrogen bonding and π-π stacking interactions. A stereochemical study of the nine-vertex polyhedra of the lanthanide ions, based on continuous shape measures, is presented. No significant magnetic interaction was found between the lanthanide(III) and the iron(III) ions.

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U2 - 10.1021/ic050648i

DO - 10.1021/ic050648i

M3 - Article

C2 - 16180855

AN - SCOPUS:26944451983

SN - 0020-1669

VL - 44

SP - 6939

EP - 6948

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 20

ER -

Magnetic properties of cyano-bridged Ln³⁺-M³⁺ complexes. Part I: Trinuclear complexes (Ln³⁺ = La, Ce, Pr, Nd, Sm; M³⁺ = Fe_LS, Co) with bpy as blocking ligand

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