TY - JOUR
T1 - Mesoporous silica-supported V-substituted heteropoly acid for efficient selective conversion of glycerol to formic acid
AU - Yuan, Ding-Jier
AU - Yang, Jingling
AU - Hengne, Amol Mahalingappa
AU - Lin, Yi Tzu
AU - Mou, Chung Yuan
AU - Huang, Kuo-Wei
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Financial support is provided by King Abdullah University of Science and Technology and by the Department of Chemistry of National Taiwan University (NTU) and Synchrotron Radiation Research Center (NSRRC, Taiwan).
PY - 2019/9/5
Y1 - 2019/9/5
N2 - V-substituted polymolybdenum phosphoric acid (PVxMo) supported on mesoporous silica was prepared and investigated as a catalyst for the oxidation of glycerol to formic acid in a batch operation. Different synthetic methods for PVxMo supported on mesoporous silica were compared. Detailed characterizations of the final products were carried out by N2 adsorption and desorption, XRD, HR-TEM, SEM, ICP-OES, XANES, NH3-TPD, and FTIR to identify the chemical properties and the porous structure of silica-supported PVxMo, as well as the strong interactions between PVxMo with the silica skeleton. These critical properties explain the bifunctionality of silica-supported PVxMo as a catalyst for the selective oxidation of glycerol to formic acid with standing stability.
AB - V-substituted polymolybdenum phosphoric acid (PVxMo) supported on mesoporous silica was prepared and investigated as a catalyst for the oxidation of glycerol to formic acid in a batch operation. Different synthetic methods for PVxMo supported on mesoporous silica were compared. Detailed characterizations of the final products were carried out by N2 adsorption and desorption, XRD, HR-TEM, SEM, ICP-OES, XANES, NH3-TPD, and FTIR to identify the chemical properties and the porous structure of silica-supported PVxMo, as well as the strong interactions between PVxMo with the silica skeleton. These critical properties explain the bifunctionality of silica-supported PVxMo as a catalyst for the selective oxidation of glycerol to formic acid with standing stability.
UR - http://hdl.handle.net/10754/658623
UR - https://linkinghub.elsevier.com/retrieve/pii/S1319610319300924
UR - http://www.scopus.com/inward/record.url?scp=85072519544&partnerID=8YFLogxK
U2 - 10.1016/j.jscs.2019.08.004
DO - 10.1016/j.jscs.2019.08.004
M3 - Article
SN - 1319-6103
VL - 24
SP - 1
EP - 8
JO - Journal of Saudi Chemical Society
JF - Journal of Saudi Chemical Society
IS - 1
ER -