Metal-organic and covalent organic frameworks as single-site catalysts

S. M.J. Rogge; A. Bavykina; J. Hajek; H. Garcia; A. I. Olivos-Suarez; A. Sepúlveda-Escribano; A. Vimont; G. Clet; P. Bazin; F. Kapteijn; M. Daturi; E. V. Ramos-Fernandez; F. X.I. Llabrés Xamena; V. Van Speybroeck; J. Gascon

doi:10.1039/c7cs00033b

Metal-organic and covalent organic frameworks as single-site catalysts

S. M.J. Rogge, A. Bavykina, J. Hajek, H. Garcia, A. I. Olivos-Suarez, A. Sepúlveda-Escribano, A. Vimont, G. Clet, P. Bazin, F. Kapteijn, M. Daturi^*, E. V. Ramos-Fernandez, F. X.I. Llabrés Xamena, V. Van Speybroeck, J. Gascon

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

869 Scopus citations

Abstract

Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.

Original language	English (US)
Pages (from-to)	3134-3184
Number of pages	51
Journal	Chemical Society Reviews
Volume	46
Issue number	11
DOIs	https://doi.org/10.1039/c7cs00033b
State	Published - Jun 7 2017
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/c7cs00033b

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Rogge, S. M. J., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A. I., Sepúlveda-Escribano, A., Vimont, A., Clet, G., Bazin, P., Kapteijn, F., Daturi, M., Ramos-Fernandez, E. V., Llabrés Xamena, F. X. I., Van Speybroeck, V., & Gascon, J. (2017). Metal-organic and covalent organic frameworks as single-site catalysts. Chemical Society Reviews, 46(11), 3134-3184. https://doi.org/10.1039/c7cs00033b

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title = "Metal-organic and covalent organic frameworks as single-site catalysts",

abstract = "Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.",

author = "Rogge, {S. M.J.} and A. Bavykina and J. Hajek and H. Garcia and Olivos-Suarez, {A. I.} and A. Sep{\'u}lveda-Escribano and A. Vimont and G. Clet and P. Bazin and F. Kapteijn and M. Daturi and Ramos-Fernandez, {E. V.} and {Llabr{\'e}s Xamena}, {F. X.I.} and {Van Speybroeck}, V. and J. Gascon",

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year = "2017",

month = jun,

day = "7",

doi = "10.1039/c7cs00033b",

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Rogge, SMJ, Bavykina, A, Hajek, J, Garcia, H, Olivos-Suarez, AI, Sepúlveda-Escribano, A, Vimont, A, Clet, G, Bazin, P, Kapteijn, F, Daturi, M, Ramos-Fernandez, EV, Llabrés Xamena, FXI, Van Speybroeck, V & Gascon, J 2017, 'Metal-organic and covalent organic frameworks as single-site catalysts', Chemical Society Reviews, vol. 46, no. 11, pp. 3134-3184. https://doi.org/10.1039/c7cs00033b

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T1 - Metal-organic and covalent organic frameworks as single-site catalysts

AU - Rogge, S. M.J.

AU - Bavykina, A.

AU - Hajek, J.

AU - Garcia, H.

AU - Olivos-Suarez, A. I.

AU - Sepúlveda-Escribano, A.

AU - Vimont, A.

AU - Clet, G.

AU - Bazin, P.

AU - Kapteijn, F.

AU - Daturi, M.

AU - Ramos-Fernandez, E. V.

AU - Llabrés Xamena, F. X.I.

AU - Van Speybroeck, V.

AU - Gascon, J.

PY - 2017/6/7

Y1 - 2017/6/7

N2 - Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.

AB - Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.

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SP - 3134

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JO - Chemical Society Reviews

JF - Chemical Society Reviews

IS - 11

ER -

Metal-organic and covalent organic frameworks as single-site catalysts

Abstract

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