Metal—organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

David T. Vodak; Matthew E. Braun; Jaheon Kim; Mohamed Eddaoudi; Omar M. Yaghi

doi:10.1039/b108684g

Metal—organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

David T. Vodak, Matthew E. Braun, Jaheon Kim, Mohamed Eddaoudi, Omar M. Yaghi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

138 Scopus citations

Abstract

Two crystalline metal—organic frameworks formulated as Zn₆(NDC)₅(OH)₂(DMF)₂·4D MF, MOF-48, and Zn₇(m-BDC)₆(OH)₄(H₂O)₂·6DMF·4H₂O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC=1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB₆.

Original language	English (US)
Pages (from-to)	2534-2535
Number of pages	2
Journal	CHEMICAL COMMUNICATIONS
Volume	1
Issue number	24
DOIs	https://doi.org/10.1039/b108684g
State	Published - Jan 1 2001
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Metal—organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units",

abstract = "Two crystalline metal—organic frameworks formulated as Zn6(NDC)5(OH)2(DMF)2·4D MF, MOF-48, and Zn7(m-BDC)6(OH)4(H2O)2·6DMF·4H2O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC=1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.",

author = "Vodak, {David T.} and Braun, {Matthew E.} and Jaheon Kim and Mohamed Eddaoudi and Yaghi, {Omar M.}",

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T1 - Metal—organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

AU - Vodak, David T.

AU - Braun, Matthew E.

AU - Kim, Jaheon

AU - Eddaoudi, Mohamed

AU - Yaghi, Omar M.

PY - 2001/1/1

Y1 - 2001/1/1

N2 - Two crystalline metal—organic frameworks formulated as Zn6(NDC)5(OH)2(DMF)2·4D MF, MOF-48, and Zn7(m-BDC)6(OH)4(H2O)2·6DMF·4H2O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC=1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.

AB - Two crystalline metal—organic frameworks formulated as Zn6(NDC)5(OH)2(DMF)2·4D MF, MOF-48, and Zn7(m-BDC)6(OH)4(H2O)2·6DMF·4H2O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC=1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.

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Metal—organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

Abstract

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