Metathesis of phosphorus-containing olefins catalysed by a cyclometallated aryloxo(chloro)neopentylidene-tungsten complex

Michel Leconte; Isabella Jourdan; Salvatore Pagano; Frédéric Lefebvre; Jean Marie Basset

doi:10.1039/C39950000857

Metathesis of phosphorus-containing olefins catalysed by a cyclometallated aryloxo(chloro)neopentylidene-tungsten complex

Michel Leconte, Isabella Jourdan, Salvatore Pagano, Frédéric Lefebvre, Jean Marie Basset^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A cyclometallated O,O′-diphenyl aryloxy(chloro)neopentylidene- tungsten complex W(OAr)(OAr)(CHCMe₃)Cl(OEt₂) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.

Original language	English (US)
Pages (from-to)	857-858
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39950000857
State	Published - 1995
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Metathesis of phosphorus-containing olefins catalysed by a cyclometallated aryloxo(chloro)neopentylidene-tungsten complex",

abstract = "A cyclometallated O,O′-diphenyl aryloxy(chloro)neopentylidene- tungsten complex W(OAr)(OAr)(CHCMe3)Cl(OEt2) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.",

author = "Michel Leconte and Isabella Jourdan and Salvatore Pagano and Fr{\'e}d{\'e}ric Lefebvre and Basset, {Jean Marie}",

year = "1995",

doi = "10.1039/C39950000857",

language = "English (US)",

pages = "857--858",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "8",

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T1 - Metathesis of phosphorus-containing olefins catalysed by a cyclometallated aryloxo(chloro)neopentylidene-tungsten complex

AU - Leconte, Michel

AU - Jourdan, Isabella

AU - Pagano, Salvatore

AU - Lefebvre, Frédéric

AU - Basset, Jean Marie

PY - 1995

Y1 - 1995

N2 - A cyclometallated O,O′-diphenyl aryloxy(chloro)neopentylidene- tungsten complex W(OAr)(OAr)(CHCMe3)Cl(OEt2) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.

AB - A cyclometallated O,O′-diphenyl aryloxy(chloro)neopentylidene- tungsten complex W(OAr)(OAr)(CHCMe3)Cl(OEt2) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.

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U2 - 10.1039/C39950000857

DO - 10.1039/C39950000857

M3 - Article

AN - SCOPUS:37049066935

SN - 0022-4936

SP - 857

EP - 858

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Metathesis of phosphorus-containing olefins catalysed by a cyclometallated aryloxo(chloro)neopentylidene-tungsten complex

Abstract

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