Methane activation by silica-supported Zr(IV) hydrides: The dihydride [(=SiO)2ZrH2] is much faster than the monohydride [(=SiO)3ZrH]

Chloé Thieuleux; Elsje Alessandra Quadrelli; Jean Marie Basset; Jens Döbler; Joachim Sauer

doi:10.1039/b404749d

Methane activation by silica-supported Zr(IV) hydrides: The dihydride [(=SiO)₂ZrH₂] is much faster than the monohydride [(=SiO)₃ZrH]

Chloé Thieuleux, Elsje Alessandra Quadrelli, Jean Marie Basset^*, Jens Döbler, Joachim Sauer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The silica-supported Zr(IV) dihydride [(SiO)₂ZrH₂] reacts quickly and completely with methane to yield [(SiO)₂ZrMe₂] through the intermediate [(SiO)₂ZrHMe], while its monohydride analogue [(SiO)₃ZrH] yields the monomethylated product [(SiO)₃ZrMe] slowly and incompletely.

Original language	English (US)
Pages (from-to)	1729-1731
Number of pages	3
Journal	CHEMICAL COMMUNICATIONS
Volume	4
Issue number	15
DOIs	https://doi.org/10.1039/b404749d
State	Published - 2004
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Methane activation by silica-supported Zr(IV) hydrides: The dihydride [(=SiO)2ZrH2] is much faster than the monohydride [(=SiO)3ZrH]",

abstract = "The silica-supported Zr(IV) dihydride [(SiO)2ZrH2] reacts quickly and completely with methane to yield [(SiO)2ZrMe2] through the intermediate [(SiO)2ZrHMe], while its monohydride analogue [(SiO)3ZrH] yields the monomethylated product [(SiO)3ZrMe] slowly and incompletely.",

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year = "2004",

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language = "English (US)",

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T1 - Methane activation by silica-supported Zr(IV) hydrides

T2 - The dihydride [(=SiO)2ZrH2] is much faster than the monohydride [(=SiO)3ZrH]

AU - Thieuleux, Chloé

AU - Quadrelli, Elsje Alessandra

AU - Basset, Jean Marie

AU - Döbler, Jens

AU - Sauer, Joachim

PY - 2004

Y1 - 2004

N2 - The silica-supported Zr(IV) dihydride [(SiO)2ZrH2] reacts quickly and completely with methane to yield [(SiO)2ZrMe2] through the intermediate [(SiO)2ZrHMe], while its monohydride analogue [(SiO)3ZrH] yields the monomethylated product [(SiO)3ZrMe] slowly and incompletely.

AB - The silica-supported Zr(IV) dihydride [(SiO)2ZrH2] reacts quickly and completely with methane to yield [(SiO)2ZrMe2] through the intermediate [(SiO)2ZrHMe], while its monohydride analogue [(SiO)3ZrH] yields the monomethylated product [(SiO)3ZrMe] slowly and incompletely.

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U2 - 10.1039/b404749d

DO - 10.1039/b404749d

M3 - Article

AN - SCOPUS:4344586758

SN - 1359-7345

VL - 4

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JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

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ER -

Methane activation by silica-supported Zr(IV) hydrides: The dihydride [(=SiO)₂ZrH₂] is much faster than the monohydride [(=SiO)₃ZrH]

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