Miscible blends of carboxylated polymers of intrinsic microporosity (cPIM-1) and Matrimid

Wai Fen Yong; Tai Shung Chung

doi:10.1016/j.polymer.2015.01.013

Miscible blends of carboxylated polymers of intrinsic microporosity (cPIM-1) and Matrimid

Wai Fen Yong, Tai Shung Chung^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

58 Scopus citations

Abstract

Miscible blends of Matrimid and carboxylated polymers of intrinsic microporosity (cPIM-1) at the molecular level have been discovered. Their miscibility has been confirmed by polarized light microscopy (PLM), atomic force microscopy (AFM), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The existence of hydrogen bonding promotes compatibility between these two polymers. A good agreement between experimental and predicted data on gas permeability and selectivity is observed. The addition of cPIM-1 in Matrimid significantly enhances the plasticization pressure for all blended membranes. A small loading of 5-10 wt% of cPIM-1 in Matrimid improves the plasticization pressure from less than 10 atm-15 atm while a higher loading of cPIM-1 shifts the plasticization pressure to 20 atm.

Original language	English (US)
Pages (from-to)	290-297
Number of pages	8
Journal	Polymer
Volume	59
DOIs	https://doi.org/10.1016/j.polymer.2015.01.013
State	Published - Feb 24 2015

Keywords

Hydrogen bonding
Miscibility
Polyimides

ASJC Scopus subject areas

Materials Chemistry
Polymers and Plastics
Organic Chemistry

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10.1016/j.polymer.2015.01.013

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title = "Miscible blends of carboxylated polymers of intrinsic microporosity (cPIM-1) and Matrimid",

abstract = "Miscible blends of Matrimid and carboxylated polymers of intrinsic microporosity (cPIM-1) at the molecular level have been discovered. Their miscibility has been confirmed by polarized light microscopy (PLM), atomic force microscopy (AFM), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The existence of hydrogen bonding promotes compatibility between these two polymers. A good agreement between experimental and predicted data on gas permeability and selectivity is observed. The addition of cPIM-1 in Matrimid significantly enhances the plasticization pressure for all blended membranes. A small loading of 5-10 wt% of cPIM-1 in Matrimid improves the plasticization pressure from less than 10 atm-15 atm while a higher loading of cPIM-1 shifts the plasticization pressure to 20 atm.",

keywords = "Hydrogen bonding, Miscibility, Polyimides",

author = "Yong, {Wai Fen} and Chung, {Tai Shung}",

year = "2015",

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day = "24",

doi = "10.1016/j.polymer.2015.01.013",

language = "English (US)",

volume = "59",

pages = "290--297",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier",

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TY - JOUR

T1 - Miscible blends of carboxylated polymers of intrinsic microporosity (cPIM-1) and Matrimid

AU - Yong, Wai Fen

AU - Chung, Tai Shung

PY - 2015/2/24

Y1 - 2015/2/24

N2 - Miscible blends of Matrimid and carboxylated polymers of intrinsic microporosity (cPIM-1) at the molecular level have been discovered. Their miscibility has been confirmed by polarized light microscopy (PLM), atomic force microscopy (AFM), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The existence of hydrogen bonding promotes compatibility between these two polymers. A good agreement between experimental and predicted data on gas permeability and selectivity is observed. The addition of cPIM-1 in Matrimid significantly enhances the plasticization pressure for all blended membranes. A small loading of 5-10 wt% of cPIM-1 in Matrimid improves the plasticization pressure from less than 10 atm-15 atm while a higher loading of cPIM-1 shifts the plasticization pressure to 20 atm.

AB - Miscible blends of Matrimid and carboxylated polymers of intrinsic microporosity (cPIM-1) at the molecular level have been discovered. Their miscibility has been confirmed by polarized light microscopy (PLM), atomic force microscopy (AFM), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The existence of hydrogen bonding promotes compatibility between these two polymers. A good agreement between experimental and predicted data on gas permeability and selectivity is observed. The addition of cPIM-1 in Matrimid significantly enhances the plasticization pressure for all blended membranes. A small loading of 5-10 wt% of cPIM-1 in Matrimid improves the plasticization pressure from less than 10 atm-15 atm while a higher loading of cPIM-1 shifts the plasticization pressure to 20 atm.

KW - Hydrogen bonding

KW - Miscibility

KW - Polyimides

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U2 - 10.1016/j.polymer.2015.01.013

DO - 10.1016/j.polymer.2015.01.013

M3 - Article

AN - SCOPUS:84921751659

SN - 0032-3861

VL - 59

SP - 290

EP - 297

JO - Polymer

JF - Polymer

ER -

Miscible blends of carboxylated polymers of intrinsic microporosity (cPIM-1) and Matrimid

Abstract

Keywords

ASJC Scopus subject areas

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