MOF@MOF core-shell vs. Janus particles and the effect of strain: Potential for guest sorption, separation and sequestration

Petra Ágota Szilágyi; Martin Lutz; Jorge Gascon; Jana Juan-Alcañiz; Jan Van Esch; Freek Kapteijn; Hans Geerlings; Bernard Dam; Roel Van De Krol

doi:10.1039/c3ce40653a

MOF@MOF core-shell vs. Janus particles and the effect of strain: Potential for guest sorption, separation and sequestration

Petra Ágota Szilágyi^*, Martin Lutz, Jorge Gascon, Jana Juan-Alcañiz, Jan Van Esch, Freek Kapteijn, Hans Geerlings, Bernard Dam, Roel Van De Krol

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The effect of strain on core-shell MOF_core@MOF_shell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core-shell particles could play a key role in sequestration of guest molecules.

Original language	English (US)
Pages (from-to)	6003-6008
Number of pages	6
Journal	CRYSTENGCOMM
Volume	15
Issue number	31
DOIs	https://doi.org/10.1039/c3ce40653a
State	Published - Aug 21 2013
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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abstract = "The effect of strain on core-shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core-shell particles could play a key role in sequestration of guest molecules.",

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doi = "10.1039/c3ce40653a",

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T1 - MOF@MOF core-shell vs. Janus particles and the effect of strain

T2 - Potential for guest sorption, separation and sequestration

AU - Szilágyi, Petra Ágota

AU - Lutz, Martin

AU - Gascon, Jorge

AU - Juan-Alcañiz, Jana

AU - Van Esch, Jan

AU - Kapteijn, Freek

AU - Geerlings, Hans

AU - Dam, Bernard

AU - Van De Krol, Roel

PY - 2013/8/21

Y1 - 2013/8/21

N2 - The effect of strain on core-shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core-shell particles could play a key role in sequestration of guest molecules.

AB - The effect of strain on core-shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core-shell particles could play a key role in sequestration of guest molecules.

UR - http://www.scopus.com/inward/record.url?scp=84880561184&partnerID=8YFLogxK

U2 - 10.1039/c3ce40653a

DO - 10.1039/c3ce40653a

M3 - Article

AN - SCOPUS:84880561184

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JO - CRYSTENGCOMM

JF - CRYSTENGCOMM

IS - 31

ER -

MOF@MOF core-shell vs. Janus particles and the effect of strain: Potential for guest sorption, separation and sequestration

Abstract

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