TY - JOUR
T1 - Multi-stage heat release in lean combustion: Insights from coupled tangential stretching rate (TSR) and computational singular perturbation (CSP) analysis
AU - AlRamadan, Abdullah
AU - Galassi, Riccardo Malpica
AU - Ciottoli, Pietro P.
AU - Valorani, Mauro
AU - Sarathy, Mani
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The simulation work was supported by King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) with funds given to the Clean Combustion Research Center. We acknowledge funding from the KAUST Clean Fuels Consortium and its member companies. MV, PPC, and RMG acknowledge the partial support from the Italian Ministry of University and Research.
PY - 2020/6/17
Y1 - 2020/6/17
N2 - There is a growing interest in leaner burning internal combustion engines as an enabler for higher thermodynamic efficiency. The extension of knock-limited compression ratio and the increase in specific heat ratio with lean combustion are key factors for boosting efficiency. Under lean burning conditions, there is emerging evidence that certain fuels exhibit unusual heat release characteristics. It has been reported that fuel/air mixtures undergo three-stage heat release or delayed high temperature heat release: starting with an initial low temperature heat release, similar to the one observed in two stage ignition, followed by an intermediate stage where thermal runaway is inhibited, and then advances to a relatively slow third stage of combustion. The focus of this study is to examine the conditions under which various fuels exhibit three stage ignition or delayed high temperature heat release. The auto-ignition of hydrocarbons/air mixtures is simulated in a closed adiabatic homogenous batch reactor where the charge is allowed to auto-ignite at constant volume vessel under predefined initial temperature and pressure. The simulations cover pressures of 10–60 bar, temperatures of 600 K–900 K, and fuel to air ratio from stoichiometry (equivalence ratio) of 0.3–1.0. Tangential stretching rate (TSR) and the computational singular perturbation Slow Importance Indices for temperature are used to identify important reactions contributing to the temperature growth rate at critical time instants of the auto-ignition process. Overall, three-stage ignition or delayed high temperature heat release is found to be present for most fuels under lean fuel/air mixtures, high pressures, and low temperature conditions. The radical termination reactions of H, OH, and HO2 during the high temperature heat release are leading factors for the distinct separation of heat release stages.
AB - There is a growing interest in leaner burning internal combustion engines as an enabler for higher thermodynamic efficiency. The extension of knock-limited compression ratio and the increase in specific heat ratio with lean combustion are key factors for boosting efficiency. Under lean burning conditions, there is emerging evidence that certain fuels exhibit unusual heat release characteristics. It has been reported that fuel/air mixtures undergo three-stage heat release or delayed high temperature heat release: starting with an initial low temperature heat release, similar to the one observed in two stage ignition, followed by an intermediate stage where thermal runaway is inhibited, and then advances to a relatively slow third stage of combustion. The focus of this study is to examine the conditions under which various fuels exhibit three stage ignition or delayed high temperature heat release. The auto-ignition of hydrocarbons/air mixtures is simulated in a closed adiabatic homogenous batch reactor where the charge is allowed to auto-ignite at constant volume vessel under predefined initial temperature and pressure. The simulations cover pressures of 10–60 bar, temperatures of 600 K–900 K, and fuel to air ratio from stoichiometry (equivalence ratio) of 0.3–1.0. Tangential stretching rate (TSR) and the computational singular perturbation Slow Importance Indices for temperature are used to identify important reactions contributing to the temperature growth rate at critical time instants of the auto-ignition process. Overall, three-stage ignition or delayed high temperature heat release is found to be present for most fuels under lean fuel/air mixtures, high pressures, and low temperature conditions. The radical termination reactions of H, OH, and HO2 during the high temperature heat release are leading factors for the distinct separation of heat release stages.
UR - http://hdl.handle.net/10754/663748
UR - https://linkinghub.elsevier.com/retrieve/pii/S0010218020302133
UR - http://www.scopus.com/inward/record.url?scp=85086448455&partnerID=8YFLogxK
U2 - 10.1016/j.combustflame.2020.05.026
DO - 10.1016/j.combustflame.2020.05.026
M3 - Article
SN - 1556-2921
VL - 219
SP - 242
EP - 257
JO - Combustion and Flame
JF - Combustion and Flame
ER -