Network diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials

Alexander Schoedel; Łukasz Wojtas; Stephen P. Kelley; Robin D. Rogers; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1002/anie.201104688

Network diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials

Alexander Schoedel, Łukasz Wojtas, Stephen P. Kelley, Robin D. Rogers, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

117 Scopus citations

Abstract

MOMs the word! In a two-step process, first a trigonal-prismatic Primary Molecular Building Block ([Cr3O(isonic)6]+, tp-PMBB-1) was formed and then it was connected to linear linkers or square-planar nodes to afford three novel highly charged cationic metal-organic materials (MOMs) with snx, snw, and stp topologies. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Pages (from-to)	11421-11424
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	50
Issue number	48
DOIs	https://doi.org/10.1002/anie.201104688
State	Published - Oct 5 2011

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.201104688

Cite this

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title = "Network diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials",

abstract = "MOMs the word! In a two-step process, first a trigonal-prismatic Primary Molecular Building Block ([Cr3O(isonic)6]+, tp-PMBB-1) was formed and then it was connected to linear linkers or square-planar nodes to afford three novel highly charged cationic metal-organic materials (MOMs) with snx, snw, and stp topologies. {\textcopyright} 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

author = "Alexander Schoedel and {\L}ukasz Wojtas and Kelley, {Stephen P.} and Rogers, {Robin D.} and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This work is supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST). We thank Dr. T. T. Ong and Dr. J. A. Perman for the help in sample characterization and S. Elsaidi for fruitful discussions.",

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AU - Schoedel, Alexander

AU - Wojtas, Łukasz

AU - Kelley, Stephen P.

AU - Rogers, Robin D.

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This work is supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST). We thank Dr. T. T. Ong and Dr. J. A. Perman for the help in sample characterization and S. Elsaidi for fruitful discussions.

PY - 2011/10/5

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N2 - MOMs the word! In a two-step process, first a trigonal-prismatic Primary Molecular Building Block ([Cr3O(isonic)6]+, tp-PMBB-1) was formed and then it was connected to linear linkers or square-planar nodes to afford three novel highly charged cationic metal-organic materials (MOMs) with snx, snw, and stp topologies. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - MOMs the word! In a two-step process, first a trigonal-prismatic Primary Molecular Building Block ([Cr3O(isonic)6]+, tp-PMBB-1) was formed and then it was connected to linear linkers or square-planar nodes to afford three novel highly charged cationic metal-organic materials (MOMs) with snx, snw, and stp topologies. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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IS - 48

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Network diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials

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CCDC 948058: Experimental Crystal Structure Determination : (mu~3~-Oxo)-hexakis(mu~2~-isonicotinamide)-nitrato-diaqua-tri-chromium hexanitrate dihydrate

CCDC 948060: Experimental Crystal Structure Determination : catena-[bis(mu3-Oxo)-dodecakis(mu3-isonicotonato)-hexaqua-hexa-chromium-hexa-silver hexanitrate bis(tetrafluoroborate) hydrate]

CCDC 948061: Experimental Crystal Structure Determination : catena-[bis(mu3-Oxo)-dodecakis(mu3-isonicotonato)-dodecaqua-tri-cadmium-hexa-chromium octanitrate acetonitrile N,N-dimethylformamide solvate]

Cite this

Network diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

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Datasets

CCDC 948058: Experimental Crystal Structure Determination : (mu~3~-Oxo)-hexakis(mu~2~-isonicotinamide)-nitrato-diaqua-tri-chromium hexanitrate dihydrate

CCDC 948060: Experimental Crystal Structure Determination : catena-[bis(mu3-Oxo)-dodecakis(mu3-isonicotonato)-hexaqua-hexa-chromium-hexa-silver hexanitrate bis(tetrafluoroborate) hydrate]

CCDC 948061: Experimental Crystal Structure Determination : catena-[bis(mu3-Oxo)-dodecakis(mu3-isonicotonato)-dodecaqua-tri-cadmium-hexa-chromium octanitrate acetonitrile N,N-dimethylformamide solvate]

Cite this