Abstract
Chiral organogermane(IV) derivatives H3GeAdCH2CO2(-)-menthyl, H3GeAdCH2CH2O(-)-bornyl and H3GeAdCH2CH2O2CCH 2O(-)-menthyl (Ad=adamantyl) have been prepared in six steps from the 1-bromoadamantane. The new optically pure organogermane reagents which have been fully characterised have been used in the preparation of heterogeneous bimetallic catalysts.
Original language | English (US) |
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Pages (from-to) | 128-136 |
Number of pages | 9 |
Journal | Journal of Organometallic Chemistry |
Volume | 580 |
Issue number | 1 |
DOIs | |
State | Published - May 15 1999 |
Externally published | Yes |
Keywords
- Germanium
- Heterogeneous bimetallic catalysts
- Optically active organogermane compounds
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry