NH 2-MIL-53(Al): A high-contrast reversible solid-state nonlinear optical switch

Pablo Serra-Crespo; Monique A. Van Der Veen; Elena Gobechiya; Kristof Houthoofd; Yaroslav Filinchuk; Christine E.A. Kirschhock; Johan A. Martens; Bert F. Sels; Dirk E. De Vos; Freek Kapteijn; Jorge Gascon

doi:10.1021/ja300655f

NH ₂-MIL-53(Al): A high-contrast reversible solid-state nonlinear optical switch

Pablo Serra-Crespo, Monique A. Van Der Veen, Elena Gobechiya, Kristof Houthoofd, Yaroslav Filinchuk, Christine E.A. Kirschhock, Johan A. Martens, Bert F. Sels, Dirk E. De Vos^*, Freek Kapteijn, Jorge Gascon

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

143 Scopus citations

Abstract

The metal-organic framework NH ₂-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

Original language	English (US)
Pages (from-to)	8314-8317
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	20
DOIs	https://doi.org/10.1021/ja300655f
State	Published - May 23 2012
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja300655f

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@article{b12db65faf584bacbcfe93a667012359,

title = "NH 2-MIL-53(Al): A high-contrast reversible solid-state nonlinear optical switch",

abstract = "The metal-organic framework NH 2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.",

author = "Pablo Serra-Crespo and {Van Der Veen}, {Monique A.} and Elena Gobechiya and Kristof Houthoofd and Yaroslav Filinchuk and Kirschhock, {Christine E.A.} and Martens, {Johan A.} and Sels, {Bert F.} and {De Vos}, {Dirk E.} and Freek Kapteijn and Jorge Gascon",

year = "2012",

month = may,

day = "23",

doi = "10.1021/ja300655f",

language = "English (US)",

volume = "134",

pages = "8314--8317",

journal = "Journal of the American Chemical Society",

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publisher = "American Chemical Society",

number = "20",

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T1 - NH 2-MIL-53(Al)

T2 - A high-contrast reversible solid-state nonlinear optical switch

AU - Serra-Crespo, Pablo

AU - Van Der Veen, Monique A.

AU - Gobechiya, Elena

AU - Houthoofd, Kristof

AU - Filinchuk, Yaroslav

AU - Kirschhock, Christine E.A.

AU - Martens, Johan A.

AU - Sels, Bert F.

AU - De Vos, Dirk E.

AU - Kapteijn, Freek

AU - Gascon, Jorge

PY - 2012/5/23

Y1 - 2012/5/23

N2 - The metal-organic framework NH 2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

AB - The metal-organic framework NH 2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

UR - http://www.scopus.com/inward/record.url?scp=84861398921&partnerID=8YFLogxK

U2 - 10.1021/ja300655f

DO - 10.1021/ja300655f

M3 - Article

AN - SCOPUS:84861398921

SN - 0002-7863

VL - 134

SP - 8314

EP - 8317

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 20

ER -

NH ₂-MIL-53(Al): A high-contrast reversible solid-state nonlinear optical switch

Abstract

ASJC Scopus subject areas

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