Nickel catalyzed dealkoxylative Csp2-Csp3 cross coupling reactions - Stereospecific synthesis of allylsilanes from enol ethers

Lin Guo; Matthias Leiendecker; Chien Chi Hsiao; Christoph Baumann; Magnus Rueping

doi:10.1039/c4cc08187k

Nickel catalyzed dealkoxylative C_sp2-C_sp3 cross coupling reactions - Stereospecific synthesis of allylsilanes from enol ethers

Lin Guo, Matthias Leiendecker, Chien Chi Hsiao, Christoph Baumann, Magnus Rueping^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

The application of cyclic and acyclic enol ethers as electrophiles in cross coupling reactions offers new possibilities for the preparation of functional compounds. A novel nickel catalyzed dealkoxylative cross coupling reaction allows access to structurally diverse allylsilanes and alcohol derivatives with high stereospecificity and in good yields under mild reaction conditions directly from the corresponding enol ethers.

Original language	English (US)
Pages (from-to)	1937-1940
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	10
DOIs	https://doi.org/10.1039/c4cc08187k
State	Published - Feb 4 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Nickel catalyzed dealkoxylative Csp2-Csp3 cross coupling reactions - Stereospecific synthesis of allylsilanes from enol ethers",

abstract = "The application of cyclic and acyclic enol ethers as electrophiles in cross coupling reactions offers new possibilities for the preparation of functional compounds. A novel nickel catalyzed dealkoxylative cross coupling reaction allows access to structurally diverse allylsilanes and alcohol derivatives with high stereospecificity and in good yields under mild reaction conditions directly from the corresponding enol ethers.",

author = "Lin Guo and Matthias Leiendecker and Hsiao, {Chien Chi} and Christoph Baumann and Magnus Rueping",

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AU - Guo, Lin

AU - Leiendecker, Matthias

AU - Hsiao, Chien Chi

AU - Baumann, Christoph

AU - Rueping, Magnus

PY - 2015/2/4

Y1 - 2015/2/4

N2 - The application of cyclic and acyclic enol ethers as electrophiles in cross coupling reactions offers new possibilities for the preparation of functional compounds. A novel nickel catalyzed dealkoxylative cross coupling reaction allows access to structurally diverse allylsilanes and alcohol derivatives with high stereospecificity and in good yields under mild reaction conditions directly from the corresponding enol ethers.

AB - The application of cyclic and acyclic enol ethers as electrophiles in cross coupling reactions offers new possibilities for the preparation of functional compounds. A novel nickel catalyzed dealkoxylative cross coupling reaction allows access to structurally diverse allylsilanes and alcohol derivatives with high stereospecificity and in good yields under mild reaction conditions directly from the corresponding enol ethers.

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U2 - 10.1039/c4cc08187k

DO - 10.1039/c4cc08187k

M3 - Article

C2 - 25532100

AN - SCOPUS:84921690402

SN - 1359-7345

VL - 51

SP - 1937

EP - 1940

JO - Chemical Communications

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IS - 10

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Nickel catalyzed dealkoxylative C_sp2-C_sp3 cross coupling reactions - Stereospecific synthesis of allylsilanes from enol ethers

Abstract

ASJC Scopus subject areas

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