Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway

Shao Chi Lee, Lin Guo, Huifeng Yue, Hsuan Hung Liao, Magnus Rueping*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

52 Scopus citations

Abstract

A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon-heteroatom bond formations in a straightforward and mild fashion.

Original languageEnglish (US)
Pages (from-to)2594-2598
Number of pages5
JournalSynlett
Volume28
Issue number19
DOIs
StatePublished - Dec 1 2017

Keywords

  • amination
  • borylation
  • decarbonylation
  • nickel catalysis
  • silylation

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint

Dive into the research topics of 'Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway'. Together they form a unique fingerprint.

Cite this