Abstract
An unprecedented nickel-catalyzed decarbonylative silylation via CO extrusion intramolecular recombination fragment coupling of unstrained and nondirecting group-Assisted silyl ketones is described. The inexpensive and readily available catalyst performs under mild reaction conditions and enables the synthesis of structurally diverse arylsilanes, including heterocyclic and natural product derivatives.
Original language | English (US) |
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Pages (from-to) | 9330-9333 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 21 |
Issue number | 23 |
DOIs | |
State | Published - Nov 8 2019 |