Nitrogen atom transfer mediated by a new PN3P-pincer nickel core: Via a putative nitrido nickel intermediate

Changguang Yao; Xiufang Wang; Kuo Wei Huang

doi:10.1039/c7cc09804a

Nitrogen atom transfer mediated by a new PN³P-pincer nickel core: Via a putative nitrido nickel intermediate

Changguang Yao, Xiufang Wang, Kuo Wei Huang^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A 2nd generation PN³P-pincer azido nickel complex (PN³P)Ni(N₃) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN³P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

Original language	English (US)
Pages (from-to)	3940-3943
Number of pages	4
Journal	CHEMICAL COMMUNICATIONS
Volume	54
Issue number	32
DOIs	https://doi.org/10.1039/c7cc09804a
State	Published - 2018

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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title = "Nitrogen atom transfer mediated by a new PN3P-pincer nickel core: Via a putative nitrido nickel intermediate",

abstract = "A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.",

author = "Changguang Yao and Xiufang Wang and Huang, {Kuo Wei}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c7cc09804a",

language = "English (US)",

volume = "54",

pages = "3940--3943",

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T1 - Nitrogen atom transfer mediated by a new PN3P-pincer nickel core

T2 - Via a putative nitrido nickel intermediate

AU - Yao, Changguang

AU - Wang, Xiufang

AU - Huang, Kuo Wei

PY - 2018

Y1 - 2018

N2 - A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

AB - A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

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U2 - 10.1039/c7cc09804a

DO - 10.1039/c7cc09804a

M3 - Article

C2 - 29461556

AN - SCOPUS:85045529897

SN - 1359-7345

VL - 54

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JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

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ER -

Nitrogen atom transfer mediated by a new PN³P-pincer nickel core: Via a putative nitrido nickel intermediate

Abstract

ASJC Scopus subject areas

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