Nitrogenated holey two-dimensional structures

Javeed Mahmood, Eun Kwang Lee, Minbok Jung, Dongbin Shin, In Yup Jeon, Sun Min Jung, Hyun Jung Choi, Jeong Min Seo, Seo Yoon Bae, So Dam Sohn, Noejung Park, Joon Hak Oh, Hyung Joon Shin, Jong Beom Baek*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

879 Scopus citations

Abstract

Recent graphene research has triggered enormous interest in new two-dimensional ordered crystals constructed by the inclusion of elements other than carbon for bandgap opening. The design of new multifunctional two-dimensional materials with proper bandgap has become an important challenge. Here we report a layered two-dimensional network structure that possesses evenly distributed holes and nitrogen atoms and a C 2 N stoichiometry in its basal plane. The two-dimensional structure can be efficiently synthesized via a simple wet-chemical reaction and confirmed with various characterization techniques, including scanning tunnelling microscopy. Furthermore, a field-effect transistor device fabricated using the material exhibits an on/off ratio of 10 7, with calculated and experimental bandgaps of approximately 1.70 and 1.96eV, respectively. In view of the simplicity of the production method and the advantages of the solution processability, the C 2 N-h2D crystal has potential for use in practical applications.

Original languageEnglish (US)
Article number6486
JournalNature Communications
Volume6
DOIs
StatePublished - Mar 2015

ASJC Scopus subject areas

  • General Chemistry
  • General Biochemistry, Genetics and Molecular Biology
  • General Physics and Astronomy

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