Non-Precious Bimetallic Catalysts for Selective Dehydrogenation of an Organic Chemical Hydride System

Anaam Shaikh Ali; Abdesslem Jedidi; Luigi Cavallo; Kazuhiro Takanabe

doi:10.1039/C5CC04016G

Non-Precious Bimetallic Catalysts for Selective Dehydrogenation of an Organic Chemical Hydride System

Anaam Shaikh Ali, Abdesslem Jedidi, Luigi Cavallo, Kazuhiro Takanabe

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46 Scopus citations

Abstract

Methylcyclohexane (MCH)-Toluene (TOL) chemical hydride cycles as a hydrogen carrier system is successful with the selective dehydrogenation reaction of MCH to TOL, which has been achieved only using precious Pt-based catalysts. Herein, we report improved selectivity using non-precious metal nickel-based bimetallic catalysts, where the second metal occupies the unselective step sites.

Original language	English (US)
Pages (from-to)	12931-12934
Number of pages	4
Journal	Chem. Commun.
Volume	51
Issue number	65
DOIs	https://doi.org/10.1039/C5CC04016G
State	Published - 2015

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abstract = "Methylcyclohexane (MCH)-Toluene (TOL) chemical hydride cycles as a hydrogen carrier system is successful with the selective dehydrogenation reaction of MCH to TOL, which has been achieved only using precious Pt-based catalysts. Herein, we report improved selectivity using non-precious metal nickel-based bimetallic catalysts, where the second metal occupies the unselective step sites.",

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AU - Shaikh Ali, Anaam

AU - Jedidi, Abdesslem

AU - Cavallo, Luigi

AU - Takanabe, Kazuhiro

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2015

Y1 - 2015

N2 - Methylcyclohexane (MCH)-Toluene (TOL) chemical hydride cycles as a hydrogen carrier system is successful with the selective dehydrogenation reaction of MCH to TOL, which has been achieved only using precious Pt-based catalysts. Herein, we report improved selectivity using non-precious metal nickel-based bimetallic catalysts, where the second metal occupies the unselective step sites.

AB - Methylcyclohexane (MCH)-Toluene (TOL) chemical hydride cycles as a hydrogen carrier system is successful with the selective dehydrogenation reaction of MCH to TOL, which has been achieved only using precious Pt-based catalysts. Herein, we report improved selectivity using non-precious metal nickel-based bimetallic catalysts, where the second metal occupies the unselective step sites.

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UR - http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC04016G

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JO - Chem. Commun.

JF - Chem. Commun.

IS - 65

ER -

Non-Precious Bimetallic Catalysts for Selective Dehydrogenation of an Organic Chemical Hydride System

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