Noninvasive functionalization of polymers of intrinsic microporosity for enhanced CO2capture

Hasmukh A. Patel; Cafer T. Yavuz

doi:10.1039/c2cc35392j

Noninvasive functionalization of polymers of intrinsic microporosity for enhanced CO2capture

Hasmukh A. Patel, Cafer T. Yavuz

Research output: Contribution to journal › Article › peer-review

196 Scopus citations

Abstract

Modifying sorbents for the purpose of improving carbon dioxide capture often results in the loss of surface area or accessible pores, or both. We report the first noninvasive functionalization of the polymers of intrinsic microporosity (PIMs) where inclusion of the amidoxime functionality in PIM-1 increases carbon dioxide capacity up to 17% and micropore surface area by 20% without losing its film forming ability. © 2012 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	9989-9991
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	80
DOIs	https://doi.org/10.1039/c2cc35392j
State	Published - Sep 12 2012
Externally published	Yes

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AB - Modifying sorbents for the purpose of improving carbon dioxide capture often results in the loss of surface area or accessible pores, or both. We report the first noninvasive functionalization of the polymers of intrinsic microporosity (PIMs) where inclusion of the amidoxime functionality in PIM-1 increases carbon dioxide capacity up to 17% and micropore surface area by 20% without losing its film forming ability. © 2012 The Royal Society of Chemistry.

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Noninvasive functionalization of polymers of intrinsic microporosity for enhanced CO2capture

Abstract

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