Novel layered perovskite oxide PrBaCuCoO5+δ as a potential cathode for intermediate-temperature solid oxide fuel cells

Ling Zhao; Qiong Nian; Beibei He; Bin Lin; Hanping Ding; Songlin Wang; Ranran Peng; Guangyao Meng; Xingqin Liu

doi:10.1016/j.jpowsour.2009.08.009

Novel layered perovskite oxide PrBaCuCoO_5+δ as a potential cathode for intermediate-temperature solid oxide fuel cells

Ling Zhao, Qiong Nian, Beibei He, Bin Lin, Hanping Ding, Songlin Wang, Ranran Peng, Guangyao Meng, Xingqin Liu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

A novel layered perovskite oxide PrBaCuCoO_5+δ (PBCCO) is employed as a potential cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). Thermal expansion and electrochemical performance on samarium-doped ceria (SDC) electrolyte are evaluated. The thermal expansion coefficient (TEC) of PrBaCuCoO_5+δ (PBCCO) is close to that of SDC electrolyte and electrical conductivity of PrBaCuCoO_5+δ (PBCCO) reaches the general required value of cathode material. Symmetrical electrochemical cell with the configuration of PrBaCuCoO_5+δ (PBCCO)/SDC/PrBaCuCoO_5+δ (PBCCO) applied for the impedance studies, the area specific resistance of PrBaCuCoO_5+δ (PBCCO) cathode is as low as 0.047 Ω cm² at 700 °C. A maximum power density of 791 mW cm^-2 is obtained at 700 °C for the single cell consisting of PrBaCuCoO_5+δ (PBCCO)/SDC/NiO-SDC. Preliminary results indicate that PrBaCuCoO_5+δ (PBCCO) is especially promising as a cathode for IT-SOFCs.

Original language	English (US)
Pages (from-to)	453-456
Number of pages	4
Journal	Journal of Power Sources
Volume	195
Issue number	2
DOIs	https://doi.org/10.1016/j.jpowsour.2009.08.009
State	Published - Jan 15 2010
Externally published	Yes

Keywords

Cathode
Electrochemical performance
Thermal expansion coefficient

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2009.08.009

Cite this

@article{4219be56aa5d4b3ea1be41d91c4355d1,

title = "Novel layered perovskite oxide PrBaCuCoO5+δ as a potential cathode for intermediate-temperature solid oxide fuel cells",

abstract = "A novel layered perovskite oxide PrBaCuCoO5+δ (PBCCO) is employed as a potential cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). Thermal expansion and electrochemical performance on samarium-doped ceria (SDC) electrolyte are evaluated. The thermal expansion coefficient (TEC) of PrBaCuCoO5+δ (PBCCO) is close to that of SDC electrolyte and electrical conductivity of PrBaCuCoO5+δ (PBCCO) reaches the general required value of cathode material. Symmetrical electrochemical cell with the configuration of PrBaCuCoO5+δ (PBCCO)/SDC/PrBaCuCoO5+δ (PBCCO) applied for the impedance studies, the area specific resistance of PrBaCuCoO5+δ (PBCCO) cathode is as low as 0.047 Ω cm2 at 700 °C. A maximum power density of 791 mW cm-2 is obtained at 700 °C for the single cell consisting of PrBaCuCoO5+δ (PBCCO)/SDC/NiO-SDC. Preliminary results indicate that PrBaCuCoO5+δ (PBCCO) is especially promising as a cathode for IT-SOFCs.",

keywords = "Cathode, Electrochemical performance, Thermal expansion coefficient",

author = "Ling Zhao and Qiong Nian and Beibei He and Bin Lin and Hanping Ding and Songlin Wang and Ranran Peng and Guangyao Meng and Xingqin Liu",

year = "2010",

month = jan,

day = "15",

doi = "10.1016/j.jpowsour.2009.08.009",

language = "English (US)",

volume = "195",

pages = "453--456",

journal = "Journal of Power Sources",

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TY - JOUR

T1 - Novel layered perovskite oxide PrBaCuCoO5+δ as a potential cathode for intermediate-temperature solid oxide fuel cells

AU - Zhao, Ling

AU - Nian, Qiong

AU - He, Beibei

AU - Lin, Bin

AU - Ding, Hanping

AU - Wang, Songlin

AU - Peng, Ranran

AU - Meng, Guangyao

AU - Liu, Xingqin

PY - 2010/1/15

Y1 - 2010/1/15

N2 - A novel layered perovskite oxide PrBaCuCoO5+δ (PBCCO) is employed as a potential cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). Thermal expansion and electrochemical performance on samarium-doped ceria (SDC) electrolyte are evaluated. The thermal expansion coefficient (TEC) of PrBaCuCoO5+δ (PBCCO) is close to that of SDC electrolyte and electrical conductivity of PrBaCuCoO5+δ (PBCCO) reaches the general required value of cathode material. Symmetrical electrochemical cell with the configuration of PrBaCuCoO5+δ (PBCCO)/SDC/PrBaCuCoO5+δ (PBCCO) applied for the impedance studies, the area specific resistance of PrBaCuCoO5+δ (PBCCO) cathode is as low as 0.047 Ω cm2 at 700 °C. A maximum power density of 791 mW cm-2 is obtained at 700 °C for the single cell consisting of PrBaCuCoO5+δ (PBCCO)/SDC/NiO-SDC. Preliminary results indicate that PrBaCuCoO5+δ (PBCCO) is especially promising as a cathode for IT-SOFCs.

AB - A novel layered perovskite oxide PrBaCuCoO5+δ (PBCCO) is employed as a potential cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). Thermal expansion and electrochemical performance on samarium-doped ceria (SDC) electrolyte are evaluated. The thermal expansion coefficient (TEC) of PrBaCuCoO5+δ (PBCCO) is close to that of SDC electrolyte and electrical conductivity of PrBaCuCoO5+δ (PBCCO) reaches the general required value of cathode material. Symmetrical electrochemical cell with the configuration of PrBaCuCoO5+δ (PBCCO)/SDC/PrBaCuCoO5+δ (PBCCO) applied for the impedance studies, the area specific resistance of PrBaCuCoO5+δ (PBCCO) cathode is as low as 0.047 Ω cm2 at 700 °C. A maximum power density of 791 mW cm-2 is obtained at 700 °C for the single cell consisting of PrBaCuCoO5+δ (PBCCO)/SDC/NiO-SDC. Preliminary results indicate that PrBaCuCoO5+δ (PBCCO) is especially promising as a cathode for IT-SOFCs.

KW - Cathode

KW - Electrochemical performance

KW - Thermal expansion coefficient

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