TY - GEN
T1 - O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7
AU - Tassel, C.
AU - Kobayashi, Y.
AU - Mitsuoka, S.
AU - Takeiri, F.
AU - Ajiro, Y.
AU - Kageyama, H.
N1 - Generated from Scopus record by KAUST IRTS on 2022-09-13
PY - 2011/1/1
Y1 - 2011/1/1
N2 - We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl)LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7. © 2011 Published under licence by IOP Publishing Ltd.
AB - We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl)LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7. © 2011 Published under licence by IOP Publishing Ltd.
UR - https://iopscience.iop.org/article/10.1088/1742-6596/320/1/012036
UR - http://www.scopus.com/inward/record.url?scp=81055133431&partnerID=8YFLogxK
U2 - 10.1088/1742-6596/320/1/012036
DO - 10.1088/1742-6596/320/1/012036
M3 - Conference contribution
BT - Journal of Physics: Conference Series
PB - Institute of Physics [email protected]
ER -