One-Dimensional Peptide Nanostructure Templated Growth of Iron Phosphate Nanostructures for Lithium-Ion Battery Cathodes

Hepi Hari Susapto; O. Ulas Kudu; Ruslan Garifullin; Eda Yilmaz; Mustafa O. Guler

doi:10.1021/acsami.6b02528

One-Dimensional Peptide Nanostructure Templated Growth of Iron Phosphate Nanostructures for Lithium-Ion Battery Cathodes

Hepi Hari Susapto, O. Ulas Kudu, Ruslan Garifullin, Eda Yilmaz, Mustafa O. Guler

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Template-directed synthesis of nanomaterials can provide benefits such as small crystalline size, high surface area, large surface-to-volume ratio, and structural stability. These properties are important for shorter distance in ion/electron movement and better electrode surface/electrolyte contact for energy storage applications. Here nanostructured FePO4 cathode materials were synthesized by using peptide nanostructures as a template inspired by biomineralization process. The amorphous, high surface area FePO4 nanostructures were utilized as a cathode for lithium-ion batteries. Discharge capacity of 155 mAh/g was achieved at C/20 current rate. The superior properties of biotemplated and nanostructured amorphous FePO4 are shown compared to template-free crystalline FePO4.

Original language	English (US)
Pages (from-to)	17421-17427
Number of pages	7
Journal	ACS Applied Materials & Interfaces
Volume	8
Issue number	27
DOIs	https://doi.org/10.1021/acsami.6b02528
State	Published - 2016
Externally published	Yes

ASJC Scopus subject areas

General Materials Science

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acsami.6b02528

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title = "One-Dimensional Peptide Nanostructure Templated Growth of Iron Phosphate Nanostructures for Lithium-Ion Battery Cathodes",

abstract = "Template-directed synthesis of nanomaterials can provide benefits such as small crystalline size, high surface area, large surface-to-volume ratio, and structural stability. These properties are important for shorter distance in ion/electron movement and better electrode surface/electrolyte contact for energy storage applications. Here nanostructured FePO4 cathode materials were synthesized by using peptide nanostructures as a template inspired by biomineralization process. The amorphous, high surface area FePO4 nanostructures were utilized as a cathode for lithium-ion batteries. Discharge capacity of 155 mAh/g was achieved at C/20 current rate. The superior properties of biotemplated and nanostructured amorphous FePO4 are shown compared to template-free crystalline FePO4.",

author = "Susapto, {Hepi Hari} and Kudu, {O. Ulas} and Ruslan Garifullin and Eda Yilmaz and Guler, {Mustafa O.}",

note = "KAUST Repository Item: Exported on 2021-07-06 Acknowledgements: This work was partially funded by TUBITAK Grant No.113M900. We thank Dr. A. Shaikh for help in peptide synthesis and M. Guler for TEM imaging.",

year = "2016",

doi = "10.1021/acsami.6b02528",

language = "English (US)",

volume = "8",

pages = "17421--17427",

journal = "ACS Applied Materials & Interfaces",

issn = "1944-8252",

publisher = "American Chemical Society",

number = "27",

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T1 - One-Dimensional Peptide Nanostructure Templated Growth of Iron Phosphate Nanostructures for Lithium-Ion Battery Cathodes

AU - Susapto, Hepi Hari

AU - Kudu, O. Ulas

AU - Garifullin, Ruslan

AU - Yilmaz, Eda

AU - Guler, Mustafa O.

N1 - KAUST Repository Item: Exported on 2021-07-06 Acknowledgements: This work was partially funded by TUBITAK Grant No.113M900. We thank Dr. A. Shaikh for help in peptide synthesis and M. Guler for TEM imaging.

PY - 2016

Y1 - 2016

N2 - Template-directed synthesis of nanomaterials can provide benefits such as small crystalline size, high surface area, large surface-to-volume ratio, and structural stability. These properties are important for shorter distance in ion/electron movement and better electrode surface/electrolyte contact for energy storage applications. Here nanostructured FePO4 cathode materials were synthesized by using peptide nanostructures as a template inspired by biomineralization process. The amorphous, high surface area FePO4 nanostructures were utilized as a cathode for lithium-ion batteries. Discharge capacity of 155 mAh/g was achieved at C/20 current rate. The superior properties of biotemplated and nanostructured amorphous FePO4 are shown compared to template-free crystalline FePO4.

AB - Template-directed synthesis of nanomaterials can provide benefits such as small crystalline size, high surface area, large surface-to-volume ratio, and structural stability. These properties are important for shorter distance in ion/electron movement and better electrode surface/electrolyte contact for energy storage applications. Here nanostructured FePO4 cathode materials were synthesized by using peptide nanostructures as a template inspired by biomineralization process. The amorphous, high surface area FePO4 nanostructures were utilized as a cathode for lithium-ion batteries. Discharge capacity of 155 mAh/g was achieved at C/20 current rate. The superior properties of biotemplated and nanostructured amorphous FePO4 are shown compared to template-free crystalline FePO4.

UR - http://hdl.handle.net/10754/670009

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JO - ACS Applied Materials & Interfaces

JF - ACS Applied Materials & Interfaces

IS - 27

ER -

One-Dimensional Peptide Nanostructure Templated Growth of Iron Phosphate Nanostructures for Lithium-Ion Battery Cathodes

Abstract

ASJC Scopus subject areas

UN SDGs

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