Oxidation of a one-dimensional coordination polymer and synthesis of the macrocyclic silver complex [Ag12(PhS2P-PS 2Ph)6(dppeS)6]

Dieter Fenske; Alexander Rothenberger; Maryam Shafaei Fallah

doi:10.1002/ejic.200400738

Oxidation of a one-dimensional coordination polymer and synthesis of the macrocyclic silver complex [Ag₁₂(PhS₂P-PS ₂Ph)₆(dppeS)₆]

Dieter Fenske, Alexander Rothenberger, Maryam Shafaei Fallah

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The cluster chemistry with functionalised trimethylsilyl re-agents was investigated. The oxidation of the one-dimensional coordination polymer 1/ _∞[{Ag₂(PhS₂P-PS₂Ph)-dppe} ·dppe]_∞ leads to the formation of [Ag ₁₂(PhS₂-P-PS₂Ph)₆(dppeS) ₆] (dppeS = Ph₂P(CH₂)₂P(S)Ph ₂]. The dianionic ligand [PhPS₂-PS₂Ph] ^2- could possibly give rise to a new class of macrocyclic transition-metal chalcogenides.

Original language	English (US)
Pages (from-to)	59-62
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	1
DOIs	https://doi.org/10.1002/ejic.200400738
State	Published - Jan 7 2005
Externally published	Yes

Keywords

Calcogenides
Macrocycle
P ligands
S ligands
Silver

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/ejic.200400738

Cite this

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title = "Oxidation of a one-dimensional coordination polymer and synthesis of the macrocyclic silver complex [Ag12(PhS2P-PS 2Ph)6(dppeS)6]",

abstract = "The cluster chemistry with functionalised trimethylsilyl re-agents was investigated. The oxidation of the one-dimensional coordination polymer 1/ ∞[{Ag2(PhS2P-PS2Ph)-dppe} ·dppe]∞ leads to the formation of [Ag 12(PhS2-P-PS2Ph)6(dppeS) 6] (dppeS = Ph2P(CH2)2P(S)Ph 2]. The dianionic ligand [PhPS2-PS2Ph] 2- could possibly give rise to a new class of macrocyclic transition-metal chalcogenides.",

keywords = "Calcogenides, Macrocycle, P ligands, S ligands, Silver",

author = "Dieter Fenske and Alexander Rothenberger and Fallah, {Maryam Shafaei}",

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language = "English (US)",

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journal = "European Journal of Inorganic Chemistry",

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T1 - Oxidation of a one-dimensional coordination polymer and synthesis of the macrocyclic silver complex [Ag12(PhS2P-PS 2Ph)6(dppeS)6]

AU - Fenske, Dieter

AU - Rothenberger, Alexander

AU - Fallah, Maryam Shafaei

PY - 2005/1/7

Y1 - 2005/1/7

N2 - The cluster chemistry with functionalised trimethylsilyl re-agents was investigated. The oxidation of the one-dimensional coordination polymer 1/ ∞[{Ag2(PhS2P-PS2Ph)-dppe} ·dppe]∞ leads to the formation of [Ag 12(PhS2-P-PS2Ph)6(dppeS) 6] (dppeS = Ph2P(CH2)2P(S)Ph 2]. The dianionic ligand [PhPS2-PS2Ph] 2- could possibly give rise to a new class of macrocyclic transition-metal chalcogenides.

AB - The cluster chemistry with functionalised trimethylsilyl re-agents was investigated. The oxidation of the one-dimensional coordination polymer 1/ ∞[{Ag2(PhS2P-PS2Ph)-dppe} ·dppe]∞ leads to the formation of [Ag 12(PhS2-P-PS2Ph)6(dppeS) 6] (dppeS = Ph2P(CH2)2P(S)Ph 2]. The dianionic ligand [PhPS2-PS2Ph] 2- could possibly give rise to a new class of macrocyclic transition-metal chalcogenides.

KW - Calcogenides

KW - Macrocycle

KW - P ligands

KW - S ligands

KW - Silver

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