TY - JOUR
T1 - Phosphate recovery as struvite within a single chamber microbial electrolysis cell
AU - Cusick, Roland D.
AU - Logan, Bruce E.
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KUS-I1-003-13
Acknowledgements: This research was supported by Award KUS-I1-003-13 from the King Abdullah University of Science and Technology (KAUST).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.
PY - 2012/3
Y1 - 2012/3
N2 - An energy efficient method of concurrent hydrogen gas and struvite (MgNH 4PO 4·6H 2O) production was investigated based on bioelectrochemically driven struvite crystallization at the cathode of a single chamber microbial electrolysis struvite-precipitation cell (MESC). The MESC cathodes were either stainless steel 304 mesh or flat plates. Phosphate removal ranged from 20% to 40%, with higher removals obtained using mesh cathodes than with flat plates. Cathode accumulated crystals were verified as struvite using a scanning electron microscope capable of energy dispersive spectroscopy (SEM-EDS). Crystal accumulation did not affect the rate of hydrogen production in struvite reactors. The rate of struvite crystallization (g/m 2-h) and hydrogen production (m 3/m 3-d) were shown to be dependent on applied voltage and cathode material. Overall energy efficiencies (substrate and electricity) were high (73±4%) and not dependent on applied voltage. These results show that MESCs may be useful both as a method for hydrogen gas and struvite production. © 2011 Elsevier Ltd.
AB - An energy efficient method of concurrent hydrogen gas and struvite (MgNH 4PO 4·6H 2O) production was investigated based on bioelectrochemically driven struvite crystallization at the cathode of a single chamber microbial electrolysis struvite-precipitation cell (MESC). The MESC cathodes were either stainless steel 304 mesh or flat plates. Phosphate removal ranged from 20% to 40%, with higher removals obtained using mesh cathodes than with flat plates. Cathode accumulated crystals were verified as struvite using a scanning electron microscope capable of energy dispersive spectroscopy (SEM-EDS). Crystal accumulation did not affect the rate of hydrogen production in struvite reactors. The rate of struvite crystallization (g/m 2-h) and hydrogen production (m 3/m 3-d) were shown to be dependent on applied voltage and cathode material. Overall energy efficiencies (substrate and electricity) were high (73±4%) and not dependent on applied voltage. These results show that MESCs may be useful both as a method for hydrogen gas and struvite production. © 2011 Elsevier Ltd.
UR - http://hdl.handle.net/10754/599180
UR - https://linkinghub.elsevier.com/retrieve/pii/S0960852411017846
UR - http://www.scopus.com/inward/record.url?scp=84856576856&partnerID=8YFLogxK
U2 - 10.1016/j.biortech.2011.12.038
DO - 10.1016/j.biortech.2011.12.038
M3 - Article
C2 - 22212692
SN - 0960-8524
VL - 107
SP - 110
EP - 115
JO - Bioresource Technology
JF - Bioresource Technology
ER -
