@article{605adc9696024d6f9a1b06004d9f6446,
title = "Photogenerated singlet oxygen over zeolite-confined carbon dots for shape selective catalysis",
abstract = "Singlet oxygen as an activated oxygen species played an important role in organic synthesis. Suitable catalyst for converting ubiquitous oxygen molecule to singlet oxygen under mild conditions has attracted a wide range of attention. Herein, carbon dots have been confined into mesopores of silicalite-1 nanocrystals framework and acted as active sites for generation of singlet oxygen. The high oxygen-adsorption capacity of zeolite nanocrystals facilitated the photocatalytic generation rate of singlet oxygen, outpacing the free-standing carbon dots for 14-fold. The integrated carbon dot-zeolite nanocrystal hybrid also exhibited a special size-dependent selectivity for organic synthesis by using the in situ formed and confined singlet oxygen as active oxygen species.",
keywords = "carbon dots, photocatalysis, shape-selective, singlet oxygen, zeolite",
author = "Yu, {Qiu Ying} and Zhai, {Guang Yao} and Cui, {Tian Lu} and Hui Su and Xue, {Zhong Hua} and Zhang, {Jun Jun} and Pauzauskie, {Peter J.} and Hirano, {Shin ichi} and Li, {Xin Hao} and Chen, {Jie Sheng}",
note = "Funding Information: This work was supported by the National Natural Science Foundation of China (21720102002, 21722103, 21673140), Shanghai Basic Research Program (16JC1401600), SJTU-MPI partner group, Shanghai Eastern Scholar Program and Shanghai Rising-Star Program (16QA1402100). We thank Prof. Huan-Ming Xiong and his coworkers (Department of Chemistry, Fudan University, Shanghai 200433, China) for providing CD for this study. Funding Information: Acknowledgements This work was supported by the National Natural Science Foundation of China (21720102002, 21722103, 21673140), Shanghai Basic Research Program (16JC1401600), SJTU-MPI partner group, Shanghai Eastern Scholar Program and Shanghai Rising-Star Program (16QA1402100). We thank Prof. Huan-Ming Xiong and his coworkers (Department of Chemistry, Fudan University, Shanghai 200433, China) for providing CD for this study. Publisher Copyright: {\textcopyright} 2019, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature.",
year = "2019",
month = apr,
day = "1",
doi = "10.1007/s11426-018-9417-4",
language = "English (US)",
volume = "62",
pages = "434--439",
journal = "Science China Chemistry",
issn = "1674-7291",
publisher = "Springer Verlag",
number = "4",
}