Poly(ethyleneimine) infused and functionalized Torlon®-silica hollow fiber sorbents for post-combustion CO2 capture

Fuyue Stephanie Li; Ying Labreche; Ryan P. Lively; Jong Suk Lee; Christopher W. Jones; William J. Koros

doi:10.1016/j.polymer.2013.11.040

Poly(ethyleneimine) infused and functionalized Torlon®-silica hollow fiber sorbents for post-combustion CO2 capture

Fuyue Stephanie Li, Ying Labreche, Ryan P. Lively, Jong Suk Lee, Christopher W. Jones, William J. Koros

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Organic-inorganic hybrid materials functionalized with amine-containing reagents are emerging as an important class of materials for capturing carbon dioxide from flue gas. Polymeric silica hollow fiber sorbents are fabricated through the proven dry-jet/wet-quench spinning process. In our study, a new technique for functionalizing polymeric silica hollow fiber sorbents with poly(ethyleneimine), followed by a post-spinning infusion step was studied. This two step process introduces a sufficient amount of poly(ethyleneimine) to the polymeric silica hybrid material support to improve the CO2 sorption capacity due to the added amine groups. The poly(ethyleneimine) infused and functionalized hollow fiber sorbents are also characterized by a thermal gravimetric analyzer (TGA) to assess their CO2 sorption capacities. © 2014 Elsevier Ltd. All rights reserved.

Original language	English (US)
Pages (from-to)	1341-1346
Number of pages	6
Journal	Polymer
Volume	55
Issue number	6
DOIs	https://doi.org/10.1016/j.polymer.2013.11.040
State	Published - Mar 2014
Externally published	Yes

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@article{22e15f4db6264238ab403bc37555e0ba,

title = "Poly(ethyleneimine) infused and functionalized Torlon{\textregistered}-silica hollow fiber sorbents for post-combustion CO2 capture",

abstract = "Organic-inorganic hybrid materials functionalized with amine-containing reagents are emerging as an important class of materials for capturing carbon dioxide from flue gas. Polymeric silica hollow fiber sorbents are fabricated through the proven dry-jet/wet-quench spinning process. In our study, a new technique for functionalizing polymeric silica hollow fiber sorbents with poly(ethyleneimine), followed by a post-spinning infusion step was studied. This two step process introduces a sufficient amount of poly(ethyleneimine) to the polymeric silica hybrid material support to improve the CO2 sorption capacity due to the added amine groups. The poly(ethyleneimine) infused and functionalized hollow fiber sorbents are also characterized by a thermal gravimetric analyzer (TGA) to assess their CO2 sorption capacities. {\textcopyright} 2014 Elsevier Ltd. All rights reserved.",

author = "Li, {Fuyue Stephanie} and Ying Labreche and Lively, {Ryan P.} and Lee, {Jong Suk} and Jones, {Christopher W.} and Koros, {William J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUSI1-011-21 Acknowledgements: This publication was based on research projects funded by King Abdullah University of Science and Technology (Award # KUSI1-011-21). The authors are grateful to Dr. Johannes Leisen for his help measuring the NMR spectra. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2014",

month = mar,

doi = "10.1016/j.polymer.2013.11.040",

language = "English (US)",

volume = "55",

pages = "1341--1346",

journal = "Polymer",

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publisher = "Elsevier B.V.",

number = "6",

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TY - JOUR

T1 - Poly(ethyleneimine) infused and functionalized Torlon®-silica hollow fiber sorbents for post-combustion CO2 capture

AU - Li, Fuyue Stephanie

AU - Labreche, Ying

AU - Lively, Ryan P.

AU - Lee, Jong Suk

AU - Jones, Christopher W.

AU - Koros, William J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUSI1-011-21 Acknowledgements: This publication was based on research projects funded by King Abdullah University of Science and Technology (Award # KUSI1-011-21). The authors are grateful to Dr. Johannes Leisen for his help measuring the NMR spectra. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2014/3

Y1 - 2014/3

N2 - Organic-inorganic hybrid materials functionalized with amine-containing reagents are emerging as an important class of materials for capturing carbon dioxide from flue gas. Polymeric silica hollow fiber sorbents are fabricated through the proven dry-jet/wet-quench spinning process. In our study, a new technique for functionalizing polymeric silica hollow fiber sorbents with poly(ethyleneimine), followed by a post-spinning infusion step was studied. This two step process introduces a sufficient amount of poly(ethyleneimine) to the polymeric silica hybrid material support to improve the CO2 sorption capacity due to the added amine groups. The poly(ethyleneimine) infused and functionalized hollow fiber sorbents are also characterized by a thermal gravimetric analyzer (TGA) to assess their CO2 sorption capacities. © 2014 Elsevier Ltd. All rights reserved.

AB - Organic-inorganic hybrid materials functionalized with amine-containing reagents are emerging as an important class of materials for capturing carbon dioxide from flue gas. Polymeric silica hollow fiber sorbents are fabricated through the proven dry-jet/wet-quench spinning process. In our study, a new technique for functionalizing polymeric silica hollow fiber sorbents with poly(ethyleneimine), followed by a post-spinning infusion step was studied. This two step process introduces a sufficient amount of poly(ethyleneimine) to the polymeric silica hybrid material support to improve the CO2 sorption capacity due to the added amine groups. The poly(ethyleneimine) infused and functionalized hollow fiber sorbents are also characterized by a thermal gravimetric analyzer (TGA) to assess their CO2 sorption capacities. © 2014 Elsevier Ltd. All rights reserved.

UR - http://hdl.handle.net/10754/599207

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U2 - 10.1016/j.polymer.2013.11.040

DO - 10.1016/j.polymer.2013.11.040

M3 - Article

SN - 0032-3861

VL - 55

SP - 1341

EP - 1346

JO - Polymer

JF - Polymer

IS - 6

ER -

Poly(ethyleneimine) infused and functionalized Torlon®-silica hollow fiber sorbents for post-combustion CO2 capture

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