Polymeric arrangements of P-Se anions and a first insight into their reactivity

Weifeng Shi; Maryam Shafaei-Fallah; Christopher E. Anson; Alexander Rothenberger

doi:10.1039/b601704e

Polymeric arrangements of P-Se anions and a first insight into their reactivity

Weifeng Shi, Maryam Shafaei-Fallah, Christopher E. Anson, Alexander Rothenberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)-Se] ₂ with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P-Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe₃]^2- or [PhPSe₂Se-SeSe₂PPh]^2- dianions are observed and the mechanisms of their formation described.

Original language	English (US)
Pages (from-to)	2979-2983
Number of pages	5
Journal	Dalton transactions
Issue number	24
DOIs	https://doi.org/10.1039/b601704e
State	Published - 2006
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Polymeric arrangements of P-Se anions and a first insight into their reactivity",

abstract = "The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)-Se] 2 with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P-Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe3]2- or [PhPSe2Se-SeSe2PPh]2- dianions are observed and the mechanisms of their formation described.",

author = "Weifeng Shi and Maryam Shafaei-Fallah and Anson, {Christopher E.} and Alexander Rothenberger",

year = "2006",

doi = "10.1039/b601704e",

language = "English (US)",

pages = "2979--2983",

journal = "Dalton transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "24",

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T1 - Polymeric arrangements of P-Se anions and a first insight into their reactivity

AU - Shi, Weifeng

AU - Shafaei-Fallah, Maryam

AU - Anson, Christopher E.

AU - Rothenberger, Alexander

PY - 2006

Y1 - 2006

N2 - The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)-Se] 2 with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P-Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe3]2- or [PhPSe2Se-SeSe2PPh]2- dianions are observed and the mechanisms of their formation described.

AB - The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)-Se] 2 with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P-Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe3]2- or [PhPSe2Se-SeSe2PPh]2- dianions are observed and the mechanisms of their formation described.

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U2 - 10.1039/b601704e

DO - 10.1039/b601704e

M3 - Article

C2 - 16770457

AN - SCOPUS:33745042991

SN - 1477-9226

SP - 2979

EP - 2983

JO - Dalton transactions

JF - Dalton transactions

IS - 24

ER -

Polymeric arrangements of P-Se anions and a first insight into their reactivity

Abstract

ASJC Scopus subject areas

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