Porous core-shell carbon fibers derived from lignin and cellulose nanofibrils

Xuezhu Xu; Jian Zhou; Long Jiang; Gilles Lubineau; Ye Chen; Xiangfa Wu; Robert Piere

doi:10.1016/j.matlet.2013.07.082

Porous core-shell carbon fibers derived from lignin and cellulose nanofibrils

Xuezhu Xu, Jian Zhou, Long Jiang, Gilles Lubineau, Ye Chen, Xiangfa Wu, Robert Piere

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

This letter reports a method to produce lignin and cellulose nanofibrils (CNFs) based porous core-shell carbon fibers via co-electrospinning followed by controlled carbonization. Lignin formed the shell of the fiber while CNF network formed the porous core. Polyacrylonitrile (PAN) was added to the lignin solution to increase its electrospinability. CNFs were surface acetylated and dispersed in silicon oil to obtain a homogenous dispersion for electrospinning the porous core. Hollow lignin fibers were also electrospun using glycerin as the core material. FT-IR measurements confirmed the CNF acetylation. SEM micrographs showed the core-shell and hollow fiber nanostructures before and after carbonization. The novel carbon fibers synthesized in this study exhibited increased surface area and porosity that are promising for many advanced applications. © 2013 Elsevier B.V.

Original language	English (US)
Pages (from-to)	175-178
Number of pages	4
Journal	Materials Letters
Volume	109
DOIs	https://doi.org/10.1016/j.matlet.2013.07.082
State	Published - Oct 2013

ASJC Scopus subject areas

Mechanics of Materials
General Materials Science
Mechanical Engineering
Condensed Matter Physics

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10.1016/j.matlet.2013.07.082

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title = "Porous core-shell carbon fibers derived from lignin and cellulose nanofibrils",

abstract = "This letter reports a method to produce lignin and cellulose nanofibrils (CNFs) based porous core-shell carbon fibers via co-electrospinning followed by controlled carbonization. Lignin formed the shell of the fiber while CNF network formed the porous core. Polyacrylonitrile (PAN) was added to the lignin solution to increase its electrospinability. CNFs were surface acetylated and dispersed in silicon oil to obtain a homogenous dispersion for electrospinning the porous core. Hollow lignin fibers were also electrospun using glycerin as the core material. FT-IR measurements confirmed the CNF acetylation. SEM micrographs showed the core-shell and hollow fiber nanostructures before and after carbonization. The novel carbon fibers synthesized in this study exhibited increased surface area and porosity that are promising for many advanced applications. {\textcopyright} 2013 Elsevier B.V.",

author = "Xuezhu Xu and Jian Zhou and Long Jiang and Gilles Lubineau and Ye Chen and Xiangfa Wu and Robert Piere",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Financial supports from ND NASA EPSCoR and KAUST Baseline are greatly appreciated.",

year = "2013",

month = oct,

doi = "10.1016/j.matlet.2013.07.082",

language = "English (US)",

volume = "109",

pages = "175--178",

journal = "Materials Letters",

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TY - JOUR

T1 - Porous core-shell carbon fibers derived from lignin and cellulose nanofibrils

AU - Xu, Xuezhu

AU - Zhou, Jian

AU - Jiang, Long

AU - Lubineau, Gilles

AU - Chen, Ye

AU - Wu, Xiangfa

AU - Piere, Robert

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Financial supports from ND NASA EPSCoR and KAUST Baseline are greatly appreciated.

PY - 2013/10

Y1 - 2013/10

N2 - This letter reports a method to produce lignin and cellulose nanofibrils (CNFs) based porous core-shell carbon fibers via co-electrospinning followed by controlled carbonization. Lignin formed the shell of the fiber while CNF network formed the porous core. Polyacrylonitrile (PAN) was added to the lignin solution to increase its electrospinability. CNFs were surface acetylated and dispersed in silicon oil to obtain a homogenous dispersion for electrospinning the porous core. Hollow lignin fibers were also electrospun using glycerin as the core material. FT-IR measurements confirmed the CNF acetylation. SEM micrographs showed the core-shell and hollow fiber nanostructures before and after carbonization. The novel carbon fibers synthesized in this study exhibited increased surface area and porosity that are promising for many advanced applications. © 2013 Elsevier B.V.

AB - This letter reports a method to produce lignin and cellulose nanofibrils (CNFs) based porous core-shell carbon fibers via co-electrospinning followed by controlled carbonization. Lignin formed the shell of the fiber while CNF network formed the porous core. Polyacrylonitrile (PAN) was added to the lignin solution to increase its electrospinability. CNFs were surface acetylated and dispersed in silicon oil to obtain a homogenous dispersion for electrospinning the porous core. Hollow lignin fibers were also electrospun using glycerin as the core material. FT-IR measurements confirmed the CNF acetylation. SEM micrographs showed the core-shell and hollow fiber nanostructures before and after carbonization. The novel carbon fibers synthesized in this study exhibited increased surface area and porosity that are promising for many advanced applications. © 2013 Elsevier B.V.

UR - http://hdl.handle.net/10754/562998

UR - https://linkinghub.elsevier.com/retrieve/pii/S0167577X13010203

UR - http://www.scopus.com/inward/record.url?scp=84881428256&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2013.07.082

DO - 10.1016/j.matlet.2013.07.082

M3 - Article

SN - 0167-577X

VL - 109

SP - 175

EP - 178

JO - Materials Letters

JF - Materials Letters

ER -

Porous core-shell carbon fibers derived from lignin and cellulose nanofibrils

Abstract

ASJC Scopus subject areas

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