@article{b48dca5956534faca5043a3de37499ae,
title = "Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination",
abstract = "Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.",
author = "Monica So and Beyzavi, {M. Hassan} and Rohan Sawhney and Osama Shekhah and Mohamed Eddaoudi and Al-Juaid, {Salih Salem} and Hupp, {Joseph T.} and Farha, {Omar K.}",
note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: O.K.F and J.T.H gratefully acknowledge funding from the Army Research Office (project number W911NF-13-1-0229). M.C.S. acknowledges support from the National Defense Science & Engineering Graduate Fellowship Program. M. H. B. acknowledges support from the Institute for Sustainability and Energy at Northwestern University. The authors are grateful for the help of Dr Diego Gomez-Gualdron for simulation of single crystals of the MOFs and the use of experimental facilities at the Integrated Molecular Structure Education and Research Center and the Northwestern University Atomic- and Nanoscale Characterization Experimental Center (NUANCE, Keck-II).",
year = "2015",
doi = "10.1039/c4cc05727a",
language = "English (US)",
volume = "51",
pages = "85--88",
journal = "Chem. Commun.",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "1",
}