Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials

Xu Xu Wang; Laurent Veyre; Frédéric Lefebvre; Joël Patarin; Jean Marie Basset

doi:10.1016/j.micromeso.2003.09.004

Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials

Xu Xu Wang, Laurent Veyre, Frédéric Lefebvre^*, Joël Patarin, Jean Marie Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Hydroxyl groups of MCM-41 dehydroxylated under vacuum at 500 °C react with tetraneopentyl zirconium, leading to the evolution of neopentane and the formation of organometallic species with the mean formula (?Si?O)₂ZrNp₂ which were fully characterized by physicochemical methods such as solid-state NMR, infrared spectroscopy, quantification of evolved gases and microanalysis. Decomposition of the resulting materials under vacuum, oxygen, water and hydrogen has been studied. The acid properties of the Zr-MCM-41 solids obtained by this way compare well to those of Zr-MCM-41 materials obtained by direct synthesis.

Original language	English (US)
Pages (from-to)	169-179
Number of pages	11
Journal	Microporous and Mesoporous Materials
Volume	66
Issue number	2-3
DOIs	https://doi.org/10.1016/j.micromeso.2003.09.004
State	Published - Dec 5 2003
Externally published	Yes

Keywords

Acidity
Mesoporous silica
Organometallic complex
Solid-state NMR
Zirconium

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

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Wang, X. X., Veyre, L., Lefebvre, F., Patarin, J., & Basset, J. M. (2003). Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials. Microporous and Mesoporous Materials, 66(2-3), 169-179. https://doi.org/10.1016/j.micromeso.2003.09.004

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title = "Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials",

abstract = "Hydroxyl groups of MCM-41 dehydroxylated under vacuum at 500 °C react with tetraneopentyl zirconium, leading to the evolution of neopentane and the formation of organometallic species with the mean formula (?Si?O)2ZrNp2 which were fully characterized by physicochemical methods such as solid-state NMR, infrared spectroscopy, quantification of evolved gases and microanalysis. Decomposition of the resulting materials under vacuum, oxygen, water and hydrogen has been studied. The acid properties of the Zr-MCM-41 solids obtained by this way compare well to those of Zr-MCM-41 materials obtained by direct synthesis.",

keywords = "Acidity, Mesoporous silica, Organometallic complex, Solid-state NMR, Zirconium",

author = "Wang, {Xu Xu} and Laurent Veyre and Fr{\'e}d{\'e}ric Lefebvre and Jo{\"e}l Patarin and Basset, {Jean Marie}",

year = "2003",

month = dec,

day = "5",

doi = "10.1016/j.micromeso.2003.09.004",

language = "English (US)",

volume = "66",

pages = "169--179",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

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}

Wang, XX, Veyre, L, Lefebvre, F, Patarin, J & Basset, JM 2003, 'Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials', Microporous and Mesoporous Materials, vol. 66, no. 2-3, pp. 169-179. https://doi.org/10.1016/j.micromeso.2003.09.004

Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials. / Wang, Xu Xu; Veyre, Laurent; Lefebvre, Frédéric et al.
In: Microporous and Mesoporous Materials, Vol. 66, No. 2-3, 05.12.2003, p. 169-179.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials

AU - Wang, Xu Xu

AU - Veyre, Laurent

AU - Lefebvre, Frédéric

AU - Patarin, Joël

AU - Basset, Jean Marie

PY - 2003/12/5

Y1 - 2003/12/5

N2 - Hydroxyl groups of MCM-41 dehydroxylated under vacuum at 500 °C react with tetraneopentyl zirconium, leading to the evolution of neopentane and the formation of organometallic species with the mean formula (?Si?O)2ZrNp2 which were fully characterized by physicochemical methods such as solid-state NMR, infrared spectroscopy, quantification of evolved gases and microanalysis. Decomposition of the resulting materials under vacuum, oxygen, water and hydrogen has been studied. The acid properties of the Zr-MCM-41 solids obtained by this way compare well to those of Zr-MCM-41 materials obtained by direct synthesis.

AB - Hydroxyl groups of MCM-41 dehydroxylated under vacuum at 500 °C react with tetraneopentyl zirconium, leading to the evolution of neopentane and the formation of organometallic species with the mean formula (?Si?O)2ZrNp2 which were fully characterized by physicochemical methods such as solid-state NMR, infrared spectroscopy, quantification of evolved gases and microanalysis. Decomposition of the resulting materials under vacuum, oxygen, water and hydrogen has been studied. The acid properties of the Zr-MCM-41 solids obtained by this way compare well to those of Zr-MCM-41 materials obtained by direct synthesis.

KW - Acidity

KW - Mesoporous silica

KW - Organometallic complex

KW - Solid-state NMR

KW - Zirconium

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U2 - 10.1016/j.micromeso.2003.09.004

DO - 10.1016/j.micromeso.2003.09.004

M3 - Article

AN - SCOPUS:0344063607

SN - 1387-1811

VL - 66

SP - 169

EP - 179

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 2-3

ER -

Preparation and characterization of zirconium containing mesoporous silicas. II. Grafting reaction of tetraneopentyl zirconium on MCM-41 and characterization of the grafted species and of the resulting materials

Abstract

Keywords

ASJC Scopus subject areas

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