Preparation of Propylene Carbonate Acrylate and Poly(propylene carbonate acrylate) Electrolyte Elastomer Gels. 13C NMR Evidence for Li+-Cyclic Carbonate Interaction

Josh H. Golden; Benjamin G.M. Chew; David B. Zax; Francis J. DiSalvo; Jean M.J. Fréchet; Jean Marie Tarascon

doi:10.1021/ma00113a054

Preparation of Propylene Carbonate Acrylate and Poly(propylene carbonate acrylate) Electrolyte Elastomer Gels. ¹³C NMR Evidence for Li⁺-Cyclic Carbonate Interaction

Josh H. Golden, Benjamin G.M. Chew, David B. Zax, Francis J. DiSalvo, Jean M.J. Fréchet, Jean Marie Tarascon

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The phosgene-free synthesis of fast curing (2-oxo-1,3-dioxolan-4-yl)methyl acrylate (propylene carbonate acrylate, PCA) is presented. Polymerization of PCA in the presence of plasticizing propylene carbonate (PC) results in the formation of reversibly swellable elastomeric gels. The ionic conductivity of poly(PCA) plasticized with 50 wt % PC and containing 1 M lithium triflate is 1.7 × 10^-5 S/cm. Evidence for Li⁺-cyclic carbonate interaction was found in ¹³C CP-MAS NMR spectroscopic analysis of the model compound poly(vinylene carbonate) containing 1 M lithium triflate.

Original language	English (US)
Pages (from-to)	3468-3470
Number of pages	3
Journal	Macromolecules
Volume	28
Issue number	9
DOIs	https://doi.org/10.1021/ma00113a054
State	Published - Apr 1 1995
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1021/ma00113a054

Cite this

@article{72350c6512b04639afa1f0fc29b1d431,

title = "Preparation of Propylene Carbonate Acrylate and Poly(propylene carbonate acrylate) Electrolyte Elastomer Gels. 13C NMR Evidence for Li+-Cyclic Carbonate Interaction",

abstract = "The phosgene-free synthesis of fast curing (2-oxo-1,3-dioxolan-4-yl)methyl acrylate (propylene carbonate acrylate, PCA) is presented. Polymerization of PCA in the presence of plasticizing propylene carbonate (PC) results in the formation of reversibly swellable elastomeric gels. The ionic conductivity of poly(PCA) plasticized with 50 wt % PC and containing 1 M lithium triflate is 1.7 × 10-5 S/cm. Evidence for Li+-cyclic carbonate interaction was found in 13C CP-MAS NMR spectroscopic analysis of the model compound poly(vinylene carbonate) containing 1 M lithium triflate.",

author = "Golden, {Josh H.} and Chew, {Benjamin G.M.} and Zax, {David B.} and DiSalvo, {Francis J.} and Fr{\'e}chet, {Jean M.J.} and Tarascon, {Jean Marie}",

year = "1995",

month = apr,

day = "1",

doi = "10.1021/ma00113a054",

language = "English (US)",

volume = "28",

pages = "3468--3470",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Preparation of Propylene Carbonate Acrylate and Poly(propylene carbonate acrylate) Electrolyte Elastomer Gels. 13C NMR Evidence for Li+-Cyclic Carbonate Interaction

AU - Golden, Josh H.

AU - Chew, Benjamin G.M.

AU - Zax, David B.

AU - DiSalvo, Francis J.

AU - Fréchet, Jean M.J.

AU - Tarascon, Jean Marie

PY - 1995/4/1

Y1 - 1995/4/1

N2 - The phosgene-free synthesis of fast curing (2-oxo-1,3-dioxolan-4-yl)methyl acrylate (propylene carbonate acrylate, PCA) is presented. Polymerization of PCA in the presence of plasticizing propylene carbonate (PC) results in the formation of reversibly swellable elastomeric gels. The ionic conductivity of poly(PCA) plasticized with 50 wt % PC and containing 1 M lithium triflate is 1.7 × 10-5 S/cm. Evidence for Li+-cyclic carbonate interaction was found in 13C CP-MAS NMR spectroscopic analysis of the model compound poly(vinylene carbonate) containing 1 M lithium triflate.

AB - The phosgene-free synthesis of fast curing (2-oxo-1,3-dioxolan-4-yl)methyl acrylate (propylene carbonate acrylate, PCA) is presented. Polymerization of PCA in the presence of plasticizing propylene carbonate (PC) results in the formation of reversibly swellable elastomeric gels. The ionic conductivity of poly(PCA) plasticized with 50 wt % PC and containing 1 M lithium triflate is 1.7 × 10-5 S/cm. Evidence for Li+-cyclic carbonate interaction was found in 13C CP-MAS NMR spectroscopic analysis of the model compound poly(vinylene carbonate) containing 1 M lithium triflate.

UR - http://www.scopus.com/inward/record.url?scp=0029290244&partnerID=8YFLogxK

U2 - 10.1021/ma00113a054

DO - 10.1021/ma00113a054

M3 - Article

AN - SCOPUS:0029290244

SN - 0024-9297

VL - 28

SP - 3468

EP - 3470

JO - Macromolecules

JF - Macromolecules

IS - 9

ER -

Preparation of Propylene Carbonate Acrylate and Poly(propylene carbonate acrylate) Electrolyte Elastomer Gels. ¹³C NMR Evidence for Li⁺-Cyclic Carbonate Interaction

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this