Production of propylene from 1-butene on highly active "bi-functional single active site" catalyst: Tungsten carbene-hydride supported on alumina

Etienne Mazoyer; Kaï Chung Szeto; Sébastien Norsic; Anthony Garron; Jean-Marie Basset; Christopher P. Nicholas; Mostafa Taoufik

doi:10.1021/cs2004054

Production of propylene from 1-butene on highly active "bi-functional single active site" catalyst: Tungsten carbene-hydride supported on alumina

Etienne Mazoyer, Kaï Chung Szeto, Sébastien Norsic, Anthony Garron, Jean-Marie Basset, Christopher P. Nicholas, Mostafa Taoufik

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

1-Butene is transformed in a continuous flow reactor over tungsten hydrides precursor W-H/Al2O3, 1, giving a promising yield into propylene at 150 °C and different pressures. Tungsten carbene-hydride single active site operates as a "bi-functional catalyst" through 1-butene isomerization on W-hydride and 1-butene/2-butenes cross-metathesis on W-carbene. This active moiety is generated in situ at the initiation steps by insertion of 1-butene on tungsten hydrides precursor W-H/Al2O3, 1 followed by α-H and β-H abstraction. © 2011 American Chemical Society.

Original language	English (US)
Pages (from-to)	1643-1646
Number of pages	4
Journal	ACS Catalysis
Volume	1
Issue number	12
DOIs	https://doi.org/10.1021/cs2004054
State	Published - Oct 26 2011

ASJC Scopus subject areas

Catalysis

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title = "Production of propylene from 1-butene on highly active {"}bi-functional single active site{"} catalyst: Tungsten carbene-hydride supported on alumina",

abstract = "1-Butene is transformed in a continuous flow reactor over tungsten hydrides precursor W-H/Al2O3, 1, giving a promising yield into propylene at 150 °C and different pressures. Tungsten carbene-hydride single active site operates as a {"}bi-functional catalyst{"} through 1-butene isomerization on W-hydride and 1-butene/2-butenes cross-metathesis on W-carbene. This active moiety is generated in situ at the initiation steps by insertion of 1-butene on tungsten hydrides precursor W-H/Al2O3, 1 followed by α-H and β-H abstraction. {\textcopyright} 2011 American Chemical Society.",

author = "Etienne Mazoyer and Szeto, {Ka{\"i} Chung} and S{\'e}bastien Norsic and Anthony Garron and Jean-Marie Basset and Nicholas, {Christopher P.} and Mostafa Taoufik",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: UOP is kindly acknowledged for generous financial support.",

year = "2011",

month = oct,

day = "26",

doi = "10.1021/cs2004054",

language = "English (US)",

volume = "1",

pages = "1643--1646",

journal = "ACS Catalysis",

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TY - JOUR

T1 - Production of propylene from 1-butene on highly active "bi-functional single active site" catalyst: Tungsten carbene-hydride supported on alumina

AU - Mazoyer, Etienne

AU - Szeto, Kaï Chung

AU - Norsic, Sébastien

AU - Garron, Anthony

AU - Basset, Jean-Marie

AU - Nicholas, Christopher P.

AU - Taoufik, Mostafa

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: UOP is kindly acknowledged for generous financial support.

PY - 2011/10/26

Y1 - 2011/10/26

N2 - 1-Butene is transformed in a continuous flow reactor over tungsten hydrides precursor W-H/Al2O3, 1, giving a promising yield into propylene at 150 °C and different pressures. Tungsten carbene-hydride single active site operates as a "bi-functional catalyst" through 1-butene isomerization on W-hydride and 1-butene/2-butenes cross-metathesis on W-carbene. This active moiety is generated in situ at the initiation steps by insertion of 1-butene on tungsten hydrides precursor W-H/Al2O3, 1 followed by α-H and β-H abstraction. © 2011 American Chemical Society.

AB - 1-Butene is transformed in a continuous flow reactor over tungsten hydrides precursor W-H/Al2O3, 1, giving a promising yield into propylene at 150 °C and different pressures. Tungsten carbene-hydride single active site operates as a "bi-functional catalyst" through 1-butene isomerization on W-hydride and 1-butene/2-butenes cross-metathesis on W-carbene. This active moiety is generated in situ at the initiation steps by insertion of 1-butene on tungsten hydrides precursor W-H/Al2O3, 1 followed by α-H and β-H abstraction. © 2011 American Chemical Society.

UR - http://hdl.handle.net/10754/561952

UR - https://pubs.acs.org/doi/10.1021/cs2004054

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DO - 10.1021/cs2004054

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SN - 2155-5435

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SP - 1643

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JO - ACS Catalysis

JF - ACS Catalysis

IS - 12

ER -

Production of propylene from 1-butene on highly active "bi-functional single active site" catalyst: Tungsten carbene-hydride supported on alumina

Abstract

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