Pyridinium Containing Amide Based Polymeric Ionic Liquids for CO2/CH4 Separation

Sonia Zulfiqar; Daniele Mantione; Omar El Tall; Fernando Ruipérez; Muhammad Ilyas Sarwar; Alexander Rothenberger; David Mecerreyes

doi:10.1021/acssuschemeng.9b01903

Pyridinium Containing Amide Based Polymeric Ionic Liquids for CO2/CH4 Separation

Sonia Zulfiqar, Daniele Mantione, Omar El Tall, Fernando Ruipérez, Muhammad Ilyas Sarwar, Alexander Rothenberger, David Mecerreyes

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Herein, we describe the design and synthesis of novel pyridinium containing amide based poly(ionic liquid)s (PAPILs) for CO2 capture and separation. Additionally, a new and unique crystal structure of pyridinium containing diamine monomer [MDAP][TFSI] is also presented. PAPILs reveal potential for CO2/CH4 separation and isosteric heat of adsorption in the physisorption range.

Original language	English (US)
Pages (from-to)	10241-10247
Number of pages	7
Journal	ACS Sustainable Chemistry and Engineering
Volume	7
Issue number	12
DOIs	https://doi.org/10.1021/acssuschemeng.9b01903
State	Published - Jun 4 2019

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title = "Pyridinium Containing Amide Based Polymeric Ionic Liquids for CO2/CH4 Separation",

abstract = "Herein, we describe the design and synthesis of novel pyridinium containing amide based poly(ionic liquid)s (PAPILs) for CO2 capture and separation. Additionally, a new and unique crystal structure of pyridinium containing diamine monomer [MDAP][TFSI] is also presented. PAPILs reveal potential for CO2/CH4 separation and isosteric heat of adsorption in the physisorption range.",

author = "Sonia Zulfiqar and Daniele Mantione and {El Tall}, Omar and Fernando Ruip{\'e}rez and Sarwar, {Muhammad Ilyas} and Alexander Rothenberger and David Mecerreyes",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Dr. Sonia Zulfiqar is highly grateful for the financial support provided by Marie Curie IIF grant “NABPIL” (No. 629050) from the European Commission under the seventh Framework Programme (FP7-PEOPLE-2013-IIF). Dr. Fernando Ruip{\'e}rez thanks the technical and human support provided by IZO-SGI, SGIker (UPV/EHU, MICINN, GV/EJ, ERDF, and ESF) for generous allocation of computational resources. Dr. Daniele Mantione is highly thankful for the support provided through EU project FP7-PEOPLE-212-ITN 316832-OLIMPIA. CCDC 1402084 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/data_request/cif, by e-mailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: (+44) 1223-336033.",

year = "2019",

month = jun,

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doi = "10.1021/acssuschemeng.9b01903",

language = "English (US)",

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journal = "ACS Sustainable Chemistry and Engineering",

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publisher = "American Chemical Society",

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AU - Zulfiqar, Sonia

AU - Mantione, Daniele

AU - El Tall, Omar

AU - Ruipérez, Fernando

AU - Sarwar, Muhammad Ilyas

AU - Rothenberger, Alexander

AU - Mecerreyes, David

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Dr. Sonia Zulfiqar is highly grateful for the financial support provided by Marie Curie IIF grant “NABPIL” (No. 629050) from the European Commission under the seventh Framework Programme (FP7-PEOPLE-2013-IIF). Dr. Fernando Ruipérez thanks the technical and human support provided by IZO-SGI, SGIker (UPV/EHU, MICINN, GV/EJ, ERDF, and ESF) for generous allocation of computational resources. Dr. Daniele Mantione is highly thankful for the support provided through EU project FP7-PEOPLE-212-ITN 316832-OLIMPIA. CCDC 1402084 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/data_request/cif, by e-mailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: (+44) 1223-336033.

PY - 2019/6/4

Y1 - 2019/6/4

N2 - Herein, we describe the design and synthesis of novel pyridinium containing amide based poly(ionic liquid)s (PAPILs) for CO2 capture and separation. Additionally, a new and unique crystal structure of pyridinium containing diamine monomer [MDAP][TFSI] is also presented. PAPILs reveal potential for CO2/CH4 separation and isosteric heat of adsorption in the physisorption range.

AB - Herein, we describe the design and synthesis of novel pyridinium containing amide based poly(ionic liquid)s (PAPILs) for CO2 capture and separation. Additionally, a new and unique crystal structure of pyridinium containing diamine monomer [MDAP][TFSI] is also presented. PAPILs reveal potential for CO2/CH4 separation and isosteric heat of adsorption in the physisorption range.

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JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 12

ER -

Pyridinium Containing Amide Based Polymeric Ionic Liquids for CO2/CH4 Separation

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