Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.

Yunling Liu; Jiantang Li; Liang Kan; Jiyang Li; Mohamed Eddaoudi

doi:10.1002/anie.202006978

Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.

Yunling Liu, Jiantang Li, Liang Kan, Jiyang Li, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.

Original language	English (US)
Journal	Angewandte Chemie (International ed. in English)
DOIs	https://doi.org/10.1002/anie.202006978
State	Published - Jul 15 2020

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10.1002/anie.202006978

https://repository.kaust.edu.sa/bitstream/10754/664243/1/Quest_anie.202006978.pdf

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@article{b4c94009adc84d569843bb865238285c,

title = "Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.",

abstract = "Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.",

author = "Yunling Liu and Jiantang Li and Liang Kan and Jiyang Li and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01",

year = "2020",

month = jul,

day = "15",

doi = "10.1002/anie.202006978",

language = "English (US)",

journal = "Angewandte Chemie (International ed. in English)",

issn = "1433-7851",

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AU - Liu, Yunling

AU - Li, Jiantang

AU - Kan, Liang

AU - Li, Jiyang

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2020/7/15

Y1 - 2020/7/15

N2 - Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.

AB - Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.

UR - http://hdl.handle.net/10754/664243

UR - https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202006978

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DO - 10.1002/anie.202006978

M3 - Article

C2 - 32662153

SN - 1433-7851

JO - Angewandte Chemie (International ed. in English)

JF - Angewandte Chemie (International ed. in English)

ER -

Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.

Abstract

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CCDC 1846425: Experimental Crystal Structure Determination : tetrakis(mu-4,5-dicarboxylatoimidazolato)-tetrakis(ethane-1,2-diamine)-tetra-cobalt heptahydrate

CCDC 1846426: Experimental Crystal Structure Determination : tetrakis(mu-4,5-dicarboxylatoimidazolato)-tetrakis(ethane-1,2-diamine)-tetra-cobalt dimethylformamide solvate nonahydrate

CCDC 1846427: Experimental Crystal Structure Determination : tetrakis(mu-4,5-dicarboxylatoimidazolato)-tetrakis(ethane-1,2-diamine)-tetra-cobalt dimethylformamide solvate dodecahydrate

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Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.

Abstract

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Datasets

CCDC 1846425: Experimental Crystal Structure Determination : tetrakis(mu-4,5-dicarboxylatoimidazolato)-tetrakis(ethane-1,2-diamine)-tetra-cobalt heptahydrate

CCDC 1846426: Experimental Crystal Structure Determination : tetrakis(mu-4,5-dicarboxylatoimidazolato)-tetrakis(ethane-1,2-diamine)-tetra-cobalt dimethylformamide solvate nonahydrate

CCDC 1846427: Experimental Crystal Structure Determination : tetrakis(mu-4,5-dicarboxylatoimidazolato)-tetrakis(ethane-1,2-diamine)-tetra-cobalt dimethylformamide solvate dodecahydrate

Cite this