Radical intermediates in the Jacobsen-Katsuki epoxidation

Luigi Cavallo; Heiko Jacobsen

doi:10.1002/(SICI)1521-3773(20000204)39:3<589::AID-ANIE589>3.0.CO;2-0

Radical intermediates in the Jacobsen-Katsuki epoxidation

Luigi Cavallo, Heiko Jacobsen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

Insight into the controversial mechanism of the Mn - salen-catalyzed epoxidation of olefins is provided in a theoretical study based on density functional theory. The calculations suggest that radical species A, but not manganaoxetanes B, are likely candidates for viable intermediates.

Original language	English (US)
Pages (from-to)	589-592
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	3
DOIs	https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<589::AID-ANIE589>3.0.CO;2-0
State	Published - Feb 4 2000
Externally published	Yes

Keywords

Asymmetric synthesis
Density functional calculations
Epoxidations
Oxidations
Radicals

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/(SICI)1521-3773(20000204)39:3<589::AID-ANIE589>3.0.CO;2-0

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abstract = "Insight into the controversial mechanism of the Mn - salen-catalyzed epoxidation of olefins is provided in a theoretical study based on density functional theory. The calculations suggest that radical species A, but not manganaoxetanes B, are likely candidates for viable intermediates.",

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KW - Asymmetric synthesis

KW - Density functional calculations

KW - Epoxidations

KW - Oxidations

KW - Radicals

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DO - 10.1002/(SICI)1521-3773(20000204)39:3<589::AID-ANIE589>3.0.CO;2-0

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Radical intermediates in the Jacobsen-Katsuki epoxidation

Abstract

Keywords

ASJC Scopus subject areas

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