Reaction of "[MnII(CH2tBu)2]" with bidentate diimine ligands: From simple base adducts to C-C activation of the ligand

Virginie Riollet; Christophe Copéret; Jean Marie Basset; Laurence Rousset; Denis Bouchu; Laurent Grosvalet; Monique Perrin

doi:10.1002/1521-3773(20020816)41:16<3025::AID-ANIE3025>3.0.CO;2-B

Reaction of "[Mn^II(CH₂tBu)₂]" with bidentate diimine ligands: From simple base adducts to C-C activation of the ligand

Virginie Riollet, Christophe Copéret^*, Jean Marie Basset, Laurence Rousset, Denis Bouchu, Laurent Grosvalet, Monique Perrin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Ligand transformations that depend on the substitution patterns of the diimine ligands occur upon their complexation with Mn¹¹ dialkyl complexes. For example the 1,3-migration of the neopentyl unit from Mn to a carbon atom and the 1,2-migration of the methyl in the putative intermediate 1 give the product 2.

Original language	English (US)
Pages (from-to)	3025-3027
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	16
DOIs	https://doi.org/10.1002/1521-3773(20020816)41:16<3025::AID-ANIE3025>3.0.CO;2-B
State	Published - Aug 16 2002
Externally published	Yes

Keywords

C-C activation
Chelates
Manganese
N ligands

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/1521-3773(20020816)41:16<3025::AID-ANIE3025>3.0.CO;2-B

Cite this

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title = "Reaction of {"}[MnII(CH2tBu)2]{"} with bidentate diimine ligands: From simple base adducts to C-C activation of the ligand",

abstract = "Ligand transformations that depend on the substitution patterns of the diimine ligands occur upon their complexation with Mn11 dialkyl complexes. For example the 1,3-migration of the neopentyl unit from Mn to a carbon atom and the 1,2-migration of the methyl in the putative intermediate 1 give the product 2.",

keywords = "C-C activation, Chelates, Manganese, N ligands",

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T2 - From simple base adducts to C-C activation of the ligand

AU - Riollet, Virginie

AU - Copéret, Christophe

AU - Basset, Jean Marie

AU - Rousset, Laurence

AU - Bouchu, Denis

AU - Grosvalet, Laurent

AU - Perrin, Monique

PY - 2002/8/16

Y1 - 2002/8/16

N2 - Ligand transformations that depend on the substitution patterns of the diimine ligands occur upon their complexation with Mn11 dialkyl complexes. For example the 1,3-migration of the neopentyl unit from Mn to a carbon atom and the 1,2-migration of the methyl in the putative intermediate 1 give the product 2.

AB - Ligand transformations that depend on the substitution patterns of the diimine ligands occur upon their complexation with Mn11 dialkyl complexes. For example the 1,3-migration of the neopentyl unit from Mn to a carbon atom and the 1,2-migration of the methyl in the putative intermediate 1 give the product 2.

KW - C-C activation

KW - Chelates

KW - Manganese

KW - N ligands

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