Reactivity of a heterocyclic As-Se compound with metal salts: Syntheses and structures of the first copper complexes and of new alkali metal salts containing As-Se anions

Thomas Zell; Weifeng Shi; Robert Langer; Lukasz Ponikiewski; Alexander Rothenberger

doi:10.1039/b715947a

Reactivity of a heterocyclic As-Se compound with metal salts: Syntheses and structures of the first copper complexes and of new alkali metal salts containing As-Se anions

Thomas Zell, Weifeng Shi, Robert Langer, Lukasz Ponikiewski, Alexander Rothenberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The structures of the new compounds [Cu₈(Ph₂As ₂Se₂)₂(PhAsSe₂)₂(dppm) ₄] (1) (dppm = bis-diphenylphosphinomethane), [Cu₄(Ph ₂As₂Se₂)₂(PPh₃) ₄] (2), [{K(18-crown-6)}₂(PhAsSe₃)] (3), [Na₁₂(PhAsSe₃)₆(15-crown-5)₆] (4) and 1/×[Na₂(PhAsSe₃)(thf)(H₂O) ₃]_× (5) are reported. 2-5 were prepared by reactions of metal thiolates with [(PhAs)₂(μ-Se)(μ-Se₂)].

Original language	English (US)
Pages (from-to)	932-937
Number of pages	6
Journal	Dalton transactions
Volume	8
Issue number	7
DOIs	https://doi.org/10.1039/b715947a
State	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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@article{26bf337b47e540ae90e3d4a68a39655e,

title = "Reactivity of a heterocyclic As-Se compound with metal salts: Syntheses and structures of the first copper complexes and of new alkali metal salts containing As-Se anions",

abstract = "The structures of the new compounds [Cu8(Ph2As 2Se2)2(PhAsSe2)2(dppm) 4] (1) (dppm = bis-diphenylphosphinomethane), [Cu4(Ph 2As2Se2)2(PPh3) 4] (2), [{K(18-crown-6)}2(PhAsSe3)] (3), [Na12(PhAsSe3)6(15-crown-5)6] (4) and 1/×[Na2(PhAsSe3)(thf)(H2O) 3]× (5) are reported. 2-5 were prepared by reactions of metal thiolates with [(PhAs)2(μ-Se)(μ-Se2)].",

author = "Thomas Zell and Weifeng Shi and Robert Langer and Lukasz Ponikiewski and Alexander Rothenberger",

year = "2008",

doi = "10.1039/b715947a",

language = "English (US)",

volume = "8",

pages = "932--937",

journal = "Dalton transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Reactivity of a heterocyclic As-Se compound with metal salts

T2 - Syntheses and structures of the first copper complexes and of new alkali metal salts containing As-Se anions

AU - Zell, Thomas

AU - Shi, Weifeng

AU - Langer, Robert

AU - Ponikiewski, Lukasz

AU - Rothenberger, Alexander

PY - 2008

Y1 - 2008

N2 - The structures of the new compounds [Cu8(Ph2As 2Se2)2(PhAsSe2)2(dppm) 4] (1) (dppm = bis-diphenylphosphinomethane), [Cu4(Ph 2As2Se2)2(PPh3) 4] (2), [{K(18-crown-6)}2(PhAsSe3)] (3), [Na12(PhAsSe3)6(15-crown-5)6] (4) and 1/×[Na2(PhAsSe3)(thf)(H2O) 3]× (5) are reported. 2-5 were prepared by reactions of metal thiolates with [(PhAs)2(μ-Se)(μ-Se2)].

AB - The structures of the new compounds [Cu8(Ph2As 2Se2)2(PhAsSe2)2(dppm) 4] (1) (dppm = bis-diphenylphosphinomethane), [Cu4(Ph 2As2Se2)2(PPh3) 4] (2), [{K(18-crown-6)}2(PhAsSe3)] (3), [Na12(PhAsSe3)6(15-crown-5)6] (4) and 1/×[Na2(PhAsSe3)(thf)(H2O) 3]× (5) are reported. 2-5 were prepared by reactions of metal thiolates with [(PhAs)2(μ-Se)(μ-Se2)].

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U2 - 10.1039/b715947a

DO - 10.1039/b715947a

M3 - Article

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AN - SCOPUS:38949109966

SN - 1477-9226

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JO - Dalton transactions

JF - Dalton transactions

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ER -

Reactivity of a heterocyclic As-Se compound with metal salts: Syntheses and structures of the first copper complexes and of new alkali metal salts containing As-Se anions

Abstract

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