TY - JOUR
T1 - Reticular Chemistry for the Construction of Highly Porous Aluminum-Based nia-Metal–Organic Frameworks
AU - Alezi, Dalal
AU - Jia, Jiangtao
AU - Bhatt, Prashant
AU - Shkurenko, Aleksander
AU - Solovyeva, Vera
AU - Chen, Zhijie
AU - Belmabkhout, Youssef
AU - Eddaoudi, Mohamed
N1 - KAUST Repository Item: Exported on 2022-07-06
Acknowledgements: The research reported in this publication was supported by funding from the King Abdullah University of Science and Technology (KAUST).
PY - 2022/6/30
Y1 - 2022/6/30
N2 - Edge-transitive nets are regarded as appropriate blueprints for the practice of reticular chemistry, and in particular, for the rational design and synthesis of functional metal–organic frameworks (MOFs). Among edge-transitive nets, type I edge-transitive nets have unique coordination figures, offering only one edge-transitive target for their associated expressed net-cBUs. Here, we report the reticulation of the binodal edge-transitive (6, 6)-c nia net in MOF chemistry, namely, the deliberate assembly of trinuclear aluminum clusters and 6-connected hexacarboxylate ligands into highly porous nia-MOFs. Further studies reveal that Al-nia-MOF-1 shows promising attributes as a storage media for oxygen (O2) at high-pressure adsorption studies.
AB - Edge-transitive nets are regarded as appropriate blueprints for the practice of reticular chemistry, and in particular, for the rational design and synthesis of functional metal–organic frameworks (MOFs). Among edge-transitive nets, type I edge-transitive nets have unique coordination figures, offering only one edge-transitive target for their associated expressed net-cBUs. Here, we report the reticulation of the binodal edge-transitive (6, 6)-c nia net in MOF chemistry, namely, the deliberate assembly of trinuclear aluminum clusters and 6-connected hexacarboxylate ligands into highly porous nia-MOFs. Further studies reveal that Al-nia-MOF-1 shows promising attributes as a storage media for oxygen (O2) at high-pressure adsorption studies.
UR - http://hdl.handle.net/10754/679621
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00756
U2 - 10.1021/acs.inorgchem.2c00756
DO - 10.1021/acs.inorgchem.2c00756
M3 - Article
C2 - 35771949
SN - 0020-1669
JO - Inorganic Chemistry
JF - Inorganic Chemistry
ER -