Reversible aggregation of porphyrins in the solid statey

Brenda Long; Osman Bakr; Francesco Stellacci

doi:10.1080/17458080802073091

Reversible aggregation of porphyrins in the solid statey

Brenda Long, Osman Bakr, Francesco Stellacci^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

This paper reports the reversible aggregation of porphyrin molecules in a thin solid film. A commercially available molecule, p-meso-tetra(4-pyridyl)porphyrin (H₂TPyP(4)), was used for these studies. Optical absorption spectroscopy of the solution and solid state forms of this molecule show that even in the solid state the molecules have enough mobility to undergo the movement required to form J-aggregates. Resonance light scattering (RLS), fluorescence spectroscopy and atomic force microscopy (AFM) are used to support these results.

Original language	English (US)
Pages (from-to)	53-60
Number of pages	8
Journal	Journal of Experimental Nanoscience
Volume	3
Issue number	1
DOIs	https://doi.org/10.1080/17458080802073091
State	Published - Mar 2008
Externally published	Yes

Keywords

Aggregation
Porphyrin
Reversible
Solid state

ASJC Scopus subject areas

Bioengineering
Biomedical Engineering
General Materials Science

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10.1080/17458080802073091

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title = "Reversible aggregation of porphyrins in the solid statey",

abstract = "This paper reports the reversible aggregation of porphyrin molecules in a thin solid film. A commercially available molecule, p-meso-tetra(4-pyridyl)porphyrin (H2TPyP(4)), was used for these studies. Optical absorption spectroscopy of the solution and solid state forms of this molecule show that even in the solid state the molecules have enough mobility to undergo the movement required to form J-aggregates. Resonance light scattering (RLS), fluorescence spectroscopy and atomic force microscopy (AFM) are used to support these results.",

keywords = "Aggregation, Porphyrin, Reversible, Solid state",

author = "Brenda Long and Osman Bakr and Francesco Stellacci",

note = "Funding Information: The financial support of the National Science Foundation (NIRT DMR-0303973) and of the Petroleum Research Fund are kindly acknowledged. FS is grateful to 3M and to DuPont for young faculty awards.",

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T1 - Reversible aggregation of porphyrins in the solid statey

AU - Long, Brenda

AU - Bakr, Osman

AU - Stellacci, Francesco

N1 - Funding Information: The financial support of the National Science Foundation (NIRT DMR-0303973) and of the Petroleum Research Fund are kindly acknowledged. FS is grateful to 3M and to DuPont for young faculty awards.

PY - 2008/3

Y1 - 2008/3

N2 - This paper reports the reversible aggregation of porphyrin molecules in a thin solid film. A commercially available molecule, p-meso-tetra(4-pyridyl)porphyrin (H2TPyP(4)), was used for these studies. Optical absorption spectroscopy of the solution and solid state forms of this molecule show that even in the solid state the molecules have enough mobility to undergo the movement required to form J-aggregates. Resonance light scattering (RLS), fluorescence spectroscopy and atomic force microscopy (AFM) are used to support these results.

AB - This paper reports the reversible aggregation of porphyrin molecules in a thin solid film. A commercially available molecule, p-meso-tetra(4-pyridyl)porphyrin (H2TPyP(4)), was used for these studies. Optical absorption spectroscopy of the solution and solid state forms of this molecule show that even in the solid state the molecules have enough mobility to undergo the movement required to form J-aggregates. Resonance light scattering (RLS), fluorescence spectroscopy and atomic force microscopy (AFM) are used to support these results.

KW - Aggregation

KW - Porphyrin

KW - Reversible

KW - Solid state

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EP - 60

JO - Journal of Experimental Nanoscience

JF - Journal of Experimental Nanoscience

IS - 1

ER -

Reversible aggregation of porphyrins in the solid statey

Abstract

Keywords

ASJC Scopus subject areas

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