Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units

Nathaniel L. Rosi; Jaheon Kim; Mohamed Eddaoudi; Banglin Chen; Michael O'Keeffe; Omar M. Yaghi

doi:10.1021/ja045123o

Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units

Nathaniel L. Rosi, Jaheon Kim, Mohamed Eddaoudi, Banglin Chen, Michael O'Keeffe^*, Omar M. Yaghi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2273 Scopus citations

Abstract

The principal structure possibilities for packing infinite rod-shaped building blocks are described. Some basic nets derived from linking simple rods (helices and ladders) are then enumerated. We demonstrate the usefulness of the concept of rod secondary building units in the design and synthesis of metal-organic frameworks (MOFs). Accordingly, we present the preparation, characterization, and crystal structures of 14 new MOFs (named MOF-69A-C and MOF-70-80) of 12 different structure types, belonging to rod packing motifs, and show how their structures are related to basic nets. The MOFs reported herein are of polytopic carboxylates and contain one of Zn, Pb, Co, Cd, Mn, or Tb. The inclusion properties of the most open members are presented as evidence that MOF structures with rod building blocks can indeed be designed to have permanent porosity and rigid architectures.

Original language	English (US)
Pages (from-to)	1504-1518
Number of pages	15
Journal	Journal of the American Chemical Society
Volume	127
Issue number	5
DOIs	https://doi.org/10.1021/ja045123o
State	Published - Feb 9 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja045123o

Cite this

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abstract = "The principal structure possibilities for packing infinite rod-shaped building blocks are described. Some basic nets derived from linking simple rods (helices and ladders) are then enumerated. We demonstrate the usefulness of the concept of rod secondary building units in the design and synthesis of metal-organic frameworks (MOFs). Accordingly, we present the preparation, characterization, and crystal structures of 14 new MOFs (named MOF-69A-C and MOF-70-80) of 12 different structure types, belonging to rod packing motifs, and show how their structures are related to basic nets. The MOFs reported herein are of polytopic carboxylates and contain one of Zn, Pb, Co, Cd, Mn, or Tb. The inclusion properties of the most open members are presented as evidence that MOF structures with rod building blocks can indeed be designed to have permanent porosity and rigid architectures.",

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AU - Rosi, Nathaniel L.

AU - Kim, Jaheon

AU - Eddaoudi, Mohamed

AU - Chen, Banglin

AU - O'Keeffe, Michael

AU - Yaghi, Omar M.

PY - 2005/2/9

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Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units

Abstract

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